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- W2134701546 abstract "Abstract The block and random copolymerization of a series of amino acid and amino ester functionalized norbornenes by ring‐opening metathesis polymerization (ROMP) induced by the well‐defined molybdenum [Mo( N ‐2,6‐ i PrC 6 H 3 )(CHCMe 2 )Ph)(OCMe 3 ) 2 ] or ruthenium [Ru(PCy) 2 Cl 2 (CHPh)] based initiators is described. The monomers are derived from the amino acids glycine, alanine, and isoleucine or the methyl esters of these amino acids and either endo‐ or exo‐ norborn‐5‐ene‐2,3‐dicarboxylic anhydride. Enantiomerically pure monomers afforded optically active polymers, and the mechanism and kinetics of the copolymerizations are investigated. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 7985–7995, 2008" @default.
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- W2134701546 date "2008-11-11" @default.
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- W2134701546 title "Copolymerization of amino acid and amino ester functionalized norbornenes via living ring-opening metathesis polymerization" @default.
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- W2134701546 doi "https://doi.org/10.1002/pola.23098" @default.
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