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- W2134724874 abstract "A new compound K8Na4[As4W19O69]·19.5H2O (1), which can be described as an extended structure of [As2W19O67(H2O)]14–, was synthesized and used as building blocks to construct the high nuclear polytungstoarsenate cluster K10Na8[(W13O28)(H2O)6(OH)4(AsW9O33)4]·56H2O (2). Polyoxoanion 2 is composed of four trivacant Keggin B-α-type [AsW9O33] units encapsulating a unique polytungstate cluster W13O32(OH)4(H2O)6, which has never observed in the polyoxometalate chemistry. Electrocatalytic studies indicate that compound 2 displays electrocatalytic activity toward the reduction of nitrate." @default.
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- W2134724874 date "2010-01-01" @default.
- W2134724874 modified "2023-09-23" @default.
- W2134724874 title "Giant Polytungstoarsenate Clusters Derived from New [As4W19O68(H2O)]14 - Building Blocks" @default.
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- W2134724874 doi "https://doi.org/10.1071/ch09446" @default.
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