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- W2134730376 startingPage "2022" @default.
- W2134730376 abstract "Abstract The morphology of micelles formed by two novel metallosurfactants has been studied by small‐angle neutron scattering (SANS) and small‐angle‐X‐ray scattering (SAXS). The two surfactants both contain a dodecyl chain as the hydrophobic moiety, but differ in the structure of the head group. The surfactants are Cu II complexes of monopendant alcohol derivatives of a) the face‐capping macrocycle 1,4,7‐triazacyclanonane (tacn), and b) an analogue based upon the tetraazamacrocycle 1,4,7,10‐tetraazacyclododecane. Here, neutron scattering has been used to study the overall size and shape of the surfactant micelles, in conjunction with X‐ray scattering to locate the metal ions. For the 1,4,7,10‐tetraazacyclododecane‐based surfactant, oblate micelles are observed, which are smaller to the prolate micelles formed by the 1,4,7‐triazacyclononane analogue. The X‐ray scattering analysis shows that the metal ions are distributed throughout the polar head‐group region, rather than at a well‐defined radius; this is in good agreement with the SANS‐derived dimensions of the micelle. Indeed, the same model for micelle morphology can be used to fit both the SANS and SAXS data." @default.
- W2134730376 created "2016-06-24" @default.
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- W2134730376 date "2004-04-07" @default.
- W2134730376 modified "2023-10-12" @default.
- W2134730376 title "The Structure of Metallomicelles" @default.
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- W2134730376 doi "https://doi.org/10.1002/chem.200305670" @default.
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