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- W2134875134 abstract "The synthesis of 2,2′-biphenylenediphenylphosphonium, 2,2′-biphenylenephenylbenzylphosphonium and 2,2′-biphenylenephenyl(p-nitrophenyl)phosphonium salts is described. The related phosphoranyl radicals I, IV and V, generated by electrochemical reduction, are measured by ESR spectroscopy. A similar procedure is followed for the radicals II and III; related phosphonium compounds are described in the literature. The small values of the phosphorus doublet splitting constants are an indication for a tetrahedron (T) like configuration of the phosphorus. The odd electron is delocalized in the aromatic ligands and the five 3-d orbitals of the phosphorus. It is shown that the spin- and odd electron density distribution depends on the electron affinity of the aryl ligands. This is confirmed by quantum chemical calculations." @default.
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- W2134875134 date "2010-09-02" @default.
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- W2134875134 title "Preparation and ESR of phosphorus spiro compounds. Part III" @default.
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- W2134875134 doi "https://doi.org/10.1002/recl.19740930503" @default.
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