FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2134945961> ?p ?o ?g. }

• W2134945961 endingPage "2903" @default.
• W2134945961 startingPage "2903" @default.
• W2134945961 abstract "Isotropic and frozen-solution ESR spectra in CH2Cl2–ClCH2CH2Cl have been recorded for the five-co-ordinate, formally cobalt(IV) complexes [Co(S2C2R2)2L][R = CN, L = PEt3; R = CF3or Ph, L = PPh3or P(OPh)3; R = C6H4Me-4, L = PPh3or PEt3; R = C6H4OMe-4, L = PPh3]. The spectra can be described by approximately axial g and 59Co hyperfine matrices with g∥=gx≈ 1.99, g⊥≈ 2.03 and A∥=Ay≈ 61 × 10–4cm –1, A⊥≈ 7 × 10–4cm–1 These parameters are interpreted to show that the cobalt electronic structure is best regarded as low-spin d5, formally CoIV, but the singly occupied molecular orbital is extensively delocalized with only about 25% cobalt 3dxzcharacter. The g and A principal axes are displaced in the xy plane by the angle α which varies from 2 to 31°, increasing with the steric bulk of R and L. This angle is related to the degree of dxz/dyz, hybridization resulting from molecular distortion from C2v, symmetry. The structures of [Co{S2C2(CF3)2}2L][L = P(OPh)3 or PPh3] were determined by X-ray diffraction methods Both complexes are approximately square pyramidal, but for L = P(OPh)3(diamagnetic in the solid state) the molecules are packed in the crystal as face-to-face pairs (Co ⋯ Co 4.11 Å). Extended-Hückel molecular-orbital calculations performed for [Co{S2C2-(CF3)2}2{P(OH)3}] support the interpretation of the ESR results." @default.
• W2134945961 created "2016-06-24" @default.
• W2134945961 creator A5018140630 @default.
• W2134945961 creator A5031481431 @default.
• W2134945961 creator A5052266151 @default.
• W2134945961 creator A5072582511 @default.
• W2134945961 creator A5076702789 @default.
• W2134945961 date "1994-01-01" @default.
• W2134945961 modified "2023-10-10" @default.
• W2134945961 title "Dithiolenes revisited: an electron spin resonance study of some five-co-ordinate cobalt complexes and the crystal structures of [Co{S2C2(CF3)2}2{P(OPh)3] and [Co{S2C2(CF3)}2(PPh3)]" @default.
• W2134945961 cites W1973014809 @default.
• W2134945961 cites W1994053038 @default.
• W2134945961 cites W1995354224 @default.
• W2134945961 cites W2002686066 @default.
• W2134945961 cites W2006335997 @default.
• W2134945961 cites W2073451133 @default.
• W2134945961 cites W2080600770 @default.
• W2134945961 cites W2081422397 @default.
• W2134945961 cites W2315007140 @default.
• W2134945961 cites W2320216808 @default.
• W2134945961 cites W2320296621 @default.
• W2134945961 cites W2320684020 @default.
• W2134945961 cites W2320722943 @default.
• W2134945961 cites W2329146555 @default.
• W2134945961 cites W3005083850 @default.
• W2134945961 cites W2088157386 @default.
• W2134945961 doi "https://doi.org/10.1039/dt9940002903" @default.
• W2134945961 hasPublicationYear "1994" @default.
• W2134945961 type Work @default.
• W2134945961 sameAs 2134945961 @default.
• W2134945961 citedByCount "13" @default.
• W2134945961 countsByYear W21349459612013 @default.
• W2134945961 countsByYear W21349459612014 @default.
• W2134945961 countsByYear W21349459612018 @default.
• W2134945961 countsByYear W21349459612020 @default.
• W2134945961 countsByYear W21349459612021 @default.
• W2134945961 countsByYear W21349459612022 @default.
• W2134945961 crossrefType "journal-article" @default.
• W2134945961 hasAuthorship W2134945961A5018140630 @default.
• W2134945961 hasAuthorship W2134945961A5031481431 @default.
• W2134945961 hasAuthorship W2134945961A5052266151 @default.
• W2134945961 hasAuthorship W2134945961A5072582511 @default.
• W2134945961 hasAuthorship W2134945961A5076702789 @default.
• W2134945961 hasConcept C115624301 @default.
• W2134945961 hasConcept C121332964 @default.
• W2134945961 hasConcept C131538251 @default.
• W2134945961 hasConcept C139210041 @default.
• W2134945961 hasConcept C139358910 @default.
• W2134945961 hasConcept C178790620 @default.
• W2134945961 hasConcept C179104552 @default.
• W2134945961 hasConcept C184779094 @default.
• W2134945961 hasConcept C185592680 @default.
• W2134945961 hasConcept C187961010 @default.
• W2134945961 hasConcept C199360897 @default.
• W2134945961 hasConcept C201194858 @default.
• W2134945961 hasConcept C2524010 @default.
• W2134945961 hasConcept C2781285689 @default.
• W2134945961 hasConcept C32909587 @default.
• W2134945961 hasConcept C33923547 @default.
• W2134945961 hasConcept C41008148 @default.
• W2134945961 hasConcept C46141821 @default.
• W2134945961 hasConcept C515602321 @default.
• W2134945961 hasConcept C70050531 @default.
• W2134945961 hasConcept C71240020 @default.
• W2134945961 hasConcept C8010536 @default.
• W2134945961 hasConceptScore W2134945961C115624301 @default.
• W2134945961 hasConceptScore W2134945961C121332964 @default.
• W2134945961 hasConceptScore W2134945961C131538251 @default.
• W2134945961 hasConceptScore W2134945961C139210041 @default.
• W2134945961 hasConceptScore W2134945961C139358910 @default.
• W2134945961 hasConceptScore W2134945961C178790620 @default.
• W2134945961 hasConceptScore W2134945961C179104552 @default.
• W2134945961 hasConceptScore W2134945961C184779094 @default.
• W2134945961 hasConceptScore W2134945961C185592680 @default.
• W2134945961 hasConceptScore W2134945961C187961010 @default.
• W2134945961 hasConceptScore W2134945961C199360897 @default.
• W2134945961 hasConceptScore W2134945961C201194858 @default.
• W2134945961 hasConceptScore W2134945961C2524010 @default.
• W2134945961 hasConceptScore W2134945961C2781285689 @default.
• W2134945961 hasConceptScore W2134945961C32909587 @default.
• W2134945961 hasConceptScore W2134945961C33923547 @default.
• W2134945961 hasConceptScore W2134945961C41008148 @default.
• W2134945961 hasConceptScore W2134945961C46141821 @default.
• W2134945961 hasConceptScore W2134945961C515602321 @default.
• W2134945961 hasConceptScore W2134945961C70050531 @default.
• W2134945961 hasConceptScore W2134945961C71240020 @default.
• W2134945961 hasConceptScore W2134945961C8010536 @default.
• W2134945961 hasIssue "20" @default.
• W2134945961 hasLocation W21349459611 @default.
• W2134945961 hasOpenAccess W2134945961 @default.
• W2134945961 hasPrimaryLocation W21349459611 @default.
• W2134945961 hasRelatedWork W108162294 @default.
• W2134945961 hasRelatedWork W1991883810 @default.
• W2134945961 hasRelatedWork W2039374736 @default.
• W2134945961 hasRelatedWork W2159319742 @default.
• W2134945961 hasRelatedWork W2167232069 @default.
• W2134945961 hasRelatedWork W2322518037 @default.
• W2134945961 hasRelatedWork W2332841977 @default.

• next