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• W2134954816 startingPage "127" @default.
• W2134954816 abstract "Abstract Selective monoarylation of aryl 2‐pyridyl ketones with a variety of arylbromides via arene sp 2 CH bond activation/functionalisation is achieved with a [RuCl 2 ( p ‐cymene)] 2 / p ‐CF 3 C 6 H 4 CO 2 H catalytic system. The reaction via a 6‐membered ruthenacycle is more difficult to perform than via a 5‐membered cyclometallate but the activation of only one ortho CH bond is unprecedentedly highly selective. A variety of functional 2‐pyridine derivatives are easily obtained. It is shown via H/D exchange that the carboxylic acid favours the reversible CH bond activation." @default.
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• W2134954816 date "2013-11-06" @default.
• W2134954816 modified "2023-10-18" @default.
• W2134954816 title "Ruthenium(II)-catalysed Functionalisation of CH Bonds via a Six-membered Cyclometallate: Monoarylation of Aryl 2-pyridyl Ketones" @default.
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• W2134954816 doi "https://doi.org/10.1002/cctc.201300752" @default.
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