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- W2135002122 abstract "1,4-Diaza-1,3-diene (=DAD) complexes of the heavy alkaline-earth metals strontium and barium have been synthesized by direct metalation of N,N′-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene (1, =DADDipp). The reaction with Sr metal afforded a mixture of the red enediamide-type derivative (DADDipp)Sr(DME)2 (2, DME = 1,2-dimethoxyethane) and black (DADDipp)2Sr(DME) (3), which contains two coordinated DAD radical anions. With barium, only the radical anion derivative (DADDipp)2Ba(DME) (4) was formed in 82% yield. For the first time, transfer of a DAD radical anion ligand from an alkaline-earth metal to a rare-earth metal has been achieved. Reaction of 4 with [{(Ph2SiO)2O}2{Li(THF)2}2]HoCl (5) afforded the novel (DAD)holmium bis(disiloxanediolate) complex [{(Ph2SiO)2O}2{Li(THF)2}2]Ho(DADDipp) (6). All new complexes (2–4 and 6) have been structurally characterized by X-ray diffraction. In addition, the radical anion complexes 3, 4, and 6 were characterized by their EPR spectra." @default.
- W2135002122 created "2016-06-24" @default.
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- W2135002122 date "2013-08-13" @default.
- W2135002122 modified "2023-09-26" @default.
- W2135002122 title "Diazadiene Complexes of the Heavy Alkaline-Earth Metals Strontium and Barium: Structures and Reactivity" @default.
- W2135002122 cites W1889685237 @default.
- W2135002122 cites W1965593981 @default.
- W2135002122 cites W1974292983 @default.
- W2135002122 cites W1974594369 @default.
- W2135002122 cites W1976405073 @default.
- W2135002122 cites W1983037021 @default.
- W2135002122 cites W1984528707 @default.
- W2135002122 cites W1986119632 @default.
- W2135002122 cites W1988921999 @default.
- W2135002122 cites W1995465404 @default.
- W2135002122 cites W1996200156 @default.
- W2135002122 cites W1998376906 @default.
- W2135002122 cites W2003925438 @default.
- W2135002122 cites W2004182290 @default.
- W2135002122 cites W2006617094 @default.
- W2135002122 cites W2007163250 @default.
- W2135002122 cites W2011574027 @default.
- W2135002122 cites W2013880822 @default.
- W2135002122 cites W2018627913 @default.
- W2135002122 cites W2019085655 @default.
- W2135002122 cites W2021628565 @default.
- W2135002122 cites W2022129332 @default.
- W2135002122 cites W2025475038 @default.
- W2135002122 cites W2026421991 @default.
- W2135002122 cites W2028165807 @default.
- W2135002122 cites W2028487674 @default.
- W2135002122 cites W2030164234 @default.
- W2135002122 cites W2032094008 @default.
- W2135002122 cites W2035634405 @default.
- W2135002122 cites W2037699857 @default.
- W2135002122 cites W2038157491 @default.
- W2135002122 cites W2041502342 @default.
- W2135002122 cites W2041765853 @default.
- W2135002122 cites W2042134453 @default.
- W2135002122 cites W2044995743 @default.
- W2135002122 cites W2045093305 @default.
- W2135002122 cites W2046136715 @default.
- W2135002122 cites W2046423181 @default.
- W2135002122 cites W2049543666 @default.
- W2135002122 cites W2050020713 @default.
- W2135002122 cites W2050023115 @default.
- W2135002122 cites W2053821173 @default.
- W2135002122 cites W2054400555 @default.
- W2135002122 cites W2057834636 @default.
- W2135002122 cites W2060159990 @default.
- W2135002122 cites W2061362639 @default.
- W2135002122 cites W2067456540 @default.
- W2135002122 cites W2067825636 @default.
- W2135002122 cites W2069490194 @default.
- W2135002122 cites W2073696982 @default.
- W2135002122 cites W2074573684 @default.
- W2135002122 cites W2078532611 @default.
- W2135002122 cites W2083461624 @default.
- W2135002122 cites W2085073264 @default.
- W2135002122 cites W2085309481 @default.
- W2135002122 cites W2086475524 @default.
- W2135002122 cites W2091956175 @default.
- W2135002122 cites W2098704029 @default.
- W2135002122 cites W2105791378 @default.
- W2135002122 cites W2111852495 @default.
- W2135002122 cites W2118275183 @default.
- W2135002122 cites W2132486002 @default.
- W2135002122 cites W2142015702 @default.
- W2135002122 cites W2154676451 @default.
- W2135002122 cites W2160238684 @default.
- W2135002122 cites W2162637930 @default.
- W2135002122 cites W2165071573 @default.
- W2135002122 cites W2165858771 @default.
- W2135002122 cites W2324091211 @default.
- W2135002122 cites W2324864314 @default.
- W2135002122 cites W2325413803 @default.
- W2135002122 cites W2331107145 @default.
- W2135002122 cites W2332883981 @default.
- W2135002122 cites W2521597623 @default.
- W2135002122 cites W2262280428 @default.
- W2135002122 doi "https://doi.org/10.1021/om400622d" @default.
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