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- W2135025522 abstract "Ternary intermetalloid cluster: The first intermetalloid M/13/15 Zintl anion [(La@In2Bi11)(μ-Bi)2(La@In2Bi11)]6− was obtained upon reaction of [InBi3]2− with [La(C5Me4H)3] in ethane-1,2-diamine (see scheme). DFT calculations served to analyze and explain the Lewis acid/base interaction upon assignment of formal charges as “Bi+←In2−”, which discriminates the anion from an isoelectronic La/Sn/Bi analogue that does not require bridging." @default.
- W2135025522 created "2016-06-24" @default.
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- W2135025522 date "2012-09-20" @default.
- W2135025522 modified "2023-10-18" @default.
- W2135025522 title "Subtle Impact of Atomic Ratio, Charge and Lewis Basicity on Structure Selection and Stability: The Zintl Anion [(La@In<sub>2</sub>Bi<sub>11</sub>)(μ<i>-</i>Bi)<sub>2</sub>(La@In<sub>2</sub>Bi<sub>11</sub>)]<sup>6−</sup>" @default.
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- W2135025522 doi "https://doi.org/10.1002/chem.201202369" @default.
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