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- W2135043395 abstract "Transient electronic absorption measurements reveal the vibrational relaxation dynamics of CH3I following excitation of the C–H stretch overtone in the gas phase and in liquid solutions. The isolated molecule relaxes through two stages of intramolecular vibrational relaxation (IVR), a fast component that occurs in a few picoseconds and a slow component that takes place in about 400 ps. In contrast, a single 5–7 ps component of IVR precedes intermolecular energy transfer (IET) to the solvent, which dissipates energy from the molecule in 50 ps, 44 ps, and 16 ps for 1 M solutions of CH3I in CCl4, CDCl3, and (CD3)2CO, respectively. The vibrational state structure suggests a model for the relaxation dynamics in which a fast component of IVR populates the states that are most strongly coupled to the initially excited C–H stretch overtone, regardless of the environment, and the remaining, weakly coupled states result in a secondary relaxation only in the absence of IET." @default.
- W2135043395 created "2016-06-24" @default.
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- W2135043395 date "2004-03-30" @default.
- W2135043395 modified "2023-09-25" @default.
- W2135043395 title "Vibrational relaxation of CH3I in the gas phase and in solution" @default.
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- W2135043395 doi "https://doi.org/10.1063/1.1676292" @default.
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