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• W2135183914 endingPage "11836" @default.
• W2135183914 startingPage "11831" @default.
• W2135183914 abstract "The polyacetylene HC2nH+ n = 2-7 cations were produced from a mixture of diacetylene with helium in a hot cathode-discharge source. After a mass-selective deposition, their absorption spectra were studied in 6 K neon matrixes. Besides the known A2Pi <-- X2Pi system, several new transitions to higher excited 2Pi electronic states of these cations have been observed. In the case of HC4H+ and HC6H+, only one new weak absorption system has been detected with the onset at 336.1 and 417.2 nm, respectively. These C2Pi <-- X2Pi transitions form a series that extends to HC10H+. Two further electronic transitions are observed for HC8H+ through to HC14H+; a weaker B2Piu <-- X2Pig and a strong E2Piu <-- X2Pig in the UV. The integrated intensity of the UV system of the polyacetylene cations exceeds that of the A2Pi <-- X2Pi transition by an order of magnitude." @default.
• W2135183914 created "2016-06-24" @default.
• W2135183914 creator A5025791798 @default.
• W2135183914 creator A5049522104 @default.
• W2135183914 creator A5052567282 @default.
• W2135183914 date "2007-10-30" @default.
• W2135183914 modified "2023-10-09" @default.
• W2135183914 title "Higher Excited Electronic Transitions of Polyacetylene Cations HC₂<i>_n</i>H⁺ <i>n</i> = 2−7 in Neon Matrixes" @default.
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• W2135183914 doi "https://doi.org/10.1021/jp075807t" @default.
• W2135183914 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17966999" @default.
• W2135183914 hasPublicationYear "2007" @default.
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