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- W2135194768 abstract "Lithium nickel oxide, a potential candidate for cathode material for lithium-ion batteries, showed a distinct deterioration after storage in air for a time. The origin of this deterioration was explored by investigating surface structure, surface species, and ionic oxidation state of fresh and stored LiNiO 2 materials. Rietveld analysis of X-ray diffraction patterns showed not only the formation of Li 2 CO 3 on the surface, but also a weakening of ordered layered structure for the stored materials. X-ray photoelectron spectroscopy revealed that Ni 3 + transforms to Ni 2 + and active oxygen species exist on the surface of stored materials. Temperature programmed desorption-mass spectroscopy measurements gave evidence that active oxygen species (O-, O - 2) occur on the surface of LiNiO 2 after storage. A surface reaction mechanism based on the transformation of Ni 3 + /Ni 2 + and the evolution of active oxygen species is proposed." @default.
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- W2135194768 date "2004-01-01" @default.
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- W2135194768 title "Origin of Deterioration for LiNiO[sub 2] Cathode Material during Storage in Air" @default.
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- W2135194768 doi "https://doi.org/10.1149/1.1738471" @default.
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