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- W2135202457 abstract "Abstract In α‐ketophosphonates, only the carbonyl group reacts with metal‐organic reagents. The resulting α‐ hydroxyalkyl‐ and α‐aryl‐α‐hydroxymethylphosphonates are hydrolysed to ketones. A side‐reaction, sometimes predominant, is the reduction of the carbonyl group in the starting materials. This is better achieved by means of sodium borohydride. The products can be hydrolysed to aldehydes or reduced to the corresponding hydrocarbons. The reactions of ethyl diethoxyphosphinylformate with Grignard compounds have been studied." @default.
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- W2135202457 date "1966-01-01" @default.
- W2135202457 modified "2023-10-18" @default.
- W2135202457 title "The Reaction of α‐Ketophosphonates with Organometallic Compounds and Sodium Borohydride" @default.
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- W2135202457 doi "https://doi.org/10.1002/ijch.196600036" @default.
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