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• W2135281197 endingPage "936" @default.
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• W2135281197 abstract "To suppress the thermal decomposition and stabilize the crystal structure of Gd 3 Al 5 O 12 ( GdAG ) garnet, GdAG was doped with significantly smaller Lu 3+ to form (Gd,Lu)AG solid solutions. The precursors for ( Gd 1− x Lu x ) 3 AG ( x = 0–0.5), with a general formula of ( NH 4 ) x Ln 3 Al 5 (OH) y ( CO 3 ) z · n H 2 O ( Ln = Gd and Lu ), were synthesized via carbonate co‐precipitation from the mixed solutions of aluminum, lutetium, and gadolinium nitrates using ammonium hydrogen carbonate as the precipitant. The results showed that 10 at.% of Lu 3+ ( x = 0.1) has been able to stabilize GdAG against its thermal decomposition to a mixture of GdAlO 3 ( GdAP ) and Al 2 O 3 phases at temperatures above 1300°C and that Lu 3+ doping effectively lowers the temperature for garnet crystallization. The precursors of x ≥ 0.3 convert to pure LnAG at a low temperature of ~1000°C via the intermediates of Ln 4 Al 2 O 9 ( LnAM ) and LnAP . The carbonate precursors are loosely agglomerated and the resultant LnAG powders show good dispersion and a fairly uniform particle morphology. The (Gd,Lu)AG solid solutions exhibit decreasing lattice parameters and increasing optical bandgaps along with more Lu 3+ incorporation." @default.
• W2135281197 created "2016-06-24" @default.
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• W2135281197 date "2011-12-09" @default.
• W2135281197 modified "2023-10-18" @default.
• W2135281197 title "Gadolinium Aluminate Garnet (Gd3Al5O12): Crystal Structure Stabilization Via Lutetium Doping and Properties of the (Gd1−xLux)3Al5O12 Solid Solutions (x = 0-0.5)" @default.
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• W2135281197 doi "https://doi.org/10.1111/j.1551-2916.2011.04991.x" @default.
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