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- W2135343600 abstract "The kinetics and equilibria of the gas phase reaction [1] tert-C 4 H 9 + + C 6 H 6 = tert-C 4 H 9 C 6 H 6 + were studied with a high ion source pressure pulsed electron beam mass spectrometer. Equilibria [1] could be observed in the temperature range 285–325 K. van't Hoff plots of the equilibrium constants led to [Formula: see text] and [Formula: see text]. The rate constants at 305 K were k lf = 1.5 × 10 −28 molecules −2 cm 6 s −1 and k lr = 2.9 × 10 −1 molecules −1 cm 3 s −1 . tert-C 4 H 9 C 6 H 6 + dissociates easily via [lr] not only because of the low dissociation energy [Formula: see text] but also because of the unusually favorable entropy [Formula: see text]. The occurrence of transalkylation reactions: tert-C 4 H 9 C 6 H 6 + + alkylbenzene = tert-C 4 H 9 alkylbenzene + + benzene, was discovered in the present work." @default.
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- W2135343600 date "1982-09-15" @default.
- W2135343600 modified "2023-09-23" @default.
- W2135343600 title "Alkylation of benzene by alkyl cations. Stability of the <i>tert</i>-butyl benzenium ion" @default.
- W2135343600 doi "https://doi.org/10.1139/v82-331" @default.
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