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- W2135361898 abstract "Interactions between surfactants, and the resultant ordering of surfactant assemblies, can be tuned by the appropriate choice of head- and tailgroups. Detailed studies of the ordering of monolayers of long-chain n-alkanoic and n-alkanol monolayers at the water−vapor interface have demonstrated that rigid-rod all-trans ordering of the tailgroups is maintained upon replacing the alcohol with a carboxylic acid headgroup. In contrast, at the water−hexane liquid−liquid interface, we demonstrate that substitution of the −CH2OH with the −COOH headgroup produces a major conformational change of the tailgroup from disordered to ordered. This is demonstrated by the electron density profiles of triacontanol (CH3(CH2)29OH) and triacontanoic acid (CH3(CH2)28COOH) monolayers at the water−hexane interface, as determined by X-ray reflectivity measurements. Molecular dynamics simulations illustrate the presence of hydrogen bonding between the triacontanoic acid headgroups that is likely responsible for the tail ordering. A simple free energy illustrates the interplay between the attractive hydrogen bonding and the ordering of the tailgroup." @default.
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- W2135361898 date "2006-09-07" @default.
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- W2135361898 title "Tail Ordering Due to Headgroup Hydrogen Bonding Interactions in Surfactant Monolayers at the Water−Oil Interface" @default.
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- W2135361898 doi "https://doi.org/10.1021/jp064120q" @default.
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