FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2135388161> ?p ?o ?g. }

• W2135388161 endingPage "8897" @default.
• W2135388161 startingPage "8897" @default.
• W2135388161 abstract "In situ formed Li/Cl phosphinidenoid complexes [Li(12-crown-4)][M(CO)5(ClPC5Me5)] 3a–c (M = Cr, Mo, W) reacted with cyclobutanone (4), cyclopentanone (5) and cyclohexanone (6) in Et2O to yield the first P-C5Me5 substituted C3-spirofused oxaphosphirane complexes 7a–c, 8a and 9a,a′. In the case of cyclopentanone and 1a the outcome of the reaction in THF was different: here the formation of 8a along with (anionic) phosphinoate complexes 14a and 15a was observed, the latter possess an unusual ring-opened oxaphosphirane and 2-cyclopentylidenecyclopentanone as co-ligands to the lithium cation. NMR, IR and MS data as well as single-crystal X-ray structures in the case of 7a–c, 8a, 9a and 15a are reported. DFT calculations on the parent 1-oxa-2-phosphaspiro[2.n]alkane pentacarbonylchromium(0) complexes 10 (a: n = 2; b: n = 3; c: n = 4; d: n = 5) revealed that both ring strain energies and G(r) values decrease significantly as the spiroring size increases. This is caused by an increase in the exocyclic α bond angle at the oxaphosphirane C3 atom, hence decreasing the s-character of the corresponding orbitals involved in endocyclic bonds at C3 and thus becoming better suited for accommodation of small ring angles." @default.
• W2135388161 created "2016-06-24" @default.
• W2135388161 creator A5023170984 @default.
• W2135388161 creator A5033746477 @default.
• W2135388161 creator A5055925650 @default.
• W2135388161 creator A5063567192 @default.
• W2135388161 creator A5082971547 @default.
• W2135388161 creator A5085441442 @default.
• W2135388161 date "2013-01-01" @default.
• W2135388161 modified "2023-10-03" @default.
• W2135388161 title "Synthesis and DFT calculations of spirooxaphosphirane complexes" @default.
• W2135388161 cites W1963559024 @default.
• W2135388161 cites W1972310344 @default.
• W2135388161 cites W1978821063 @default.
• W2135388161 cites W1981636448 @default.
• W2135388161 cites W1993383767 @default.
• W2135388161 cites W1994682604 @default.
• W2135388161 cites W1995736678 @default.
• W2135388161 cites W1996846370 @default.
• W2135388161 cites W1999429114 @default.
• W2135388161 cites W2001673489 @default.
• W2135388161 cites W2011078640 @default.
• W2135388161 cites W2015723183 @default.
• W2135388161 cites W2023271753 @default.
• W2135388161 cites W2025590935 @default.
• W2135388161 cites W2026326643 @default.
• W2135388161 cites W2026429910 @default.
• W2135388161 cites W2033281962 @default.
• W2135388161 cites W2034725750 @default.
• W2135388161 cites W2035198476 @default.
• W2135388161 cites W2039293281 @default.
• W2135388161 cites W2044497791 @default.
• W2135388161 cites W2049124740 @default.
• W2135388161 cites W2049584011 @default.
• W2135388161 cites W2051469879 @default.
• W2135388161 cites W2053660526 @default.
• W2135388161 cites W2055122330 @default.
• W2135388161 cites W2055563809 @default.
• W2135388161 cites W2058210956 @default.
• W2135388161 cites W2058749895 @default.
• W2135388161 cites W2065643629 @default.
• W2135388161 cites W2067718414 @default.
• W2135388161 cites W2070203126 @default.
• W2135388161 cites W2073328513 @default.
• W2135388161 cites W2085966856 @default.
• W2135388161 cites W2086451633 @default.
• W2135388161 cites W2092157292 @default.
• W2135388161 cites W2096817557 @default.
• W2135388161 cites W2104692825 @default.
• W2135388161 cites W2112267308 @default.
• W2135388161 cites W2131350133 @default.
• W2135388161 cites W2136235501 @default.
• W2135388161 cites W2137013960 @default.
• W2135388161 cites W2141074519 @default.
• W2135388161 cites W2143981217 @default.
• W2135388161 cites W2156559244 @default.
• W2135388161 cites W2164977927 @default.
• W2135388161 cites W2323585291 @default.
• W2135388161 cites W2325662916 @default.
• W2135388161 cites W2328942505 @default.
• W2135388161 cites W2333663508 @default.
• W2135388161 cites W2338316587 @default.
• W2135388161 cites W2950858073 @default.
• W2135388161 cites W2951667316 @default.
• W2135388161 cites W2953261283 @default.
• W2135388161 cites W4236048302 @default.
• W2135388161 doi "https://doi.org/10.1039/c3dt50556a" @default.
• W2135388161 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23660754" @default.
• W2135388161 hasPublicationYear "2013" @default.
• W2135388161 type Work @default.
• W2135388161 sameAs 2135388161 @default.
• W2135388161 citedByCount "25" @default.
• W2135388161 countsByYear W21353881612014 @default.
• W2135388161 countsByYear W21353881612015 @default.
• W2135388161 countsByYear W21353881612016 @default.
• W2135388161 countsByYear W21353881612017 @default.
• W2135388161 countsByYear W21353881612018 @default.
• W2135388161 countsByYear W21353881612020 @default.
• W2135388161 countsByYear W21353881612021 @default.
• W2135388161 countsByYear W21353881612022 @default.
• W2135388161 crossrefType "journal-article" @default.
• W2135388161 hasAuthorship W2135388161A5023170984 @default.
• W2135388161 hasAuthorship W2135388161A5033746477 @default.
• W2135388161 hasAuthorship W2135388161A5055925650 @default.
• W2135388161 hasAuthorship W2135388161A5063567192 @default.
• W2135388161 hasAuthorship W2135388161A5082971547 @default.
• W2135388161 hasAuthorship W2135388161A5085441442 @default.
• W2135388161 hasConcept C107111320 @default.
• W2135388161 hasConcept C134018914 @default.
• W2135388161 hasConcept C134121241 @default.
• W2135388161 hasConcept C161790260 @default.
• W2135388161 hasConcept C178790620 @default.
• W2135388161 hasConcept C185592680 @default.
• W2135388161 hasConcept C191897082 @default.
• W2135388161 hasConcept C192562407 @default.
• W2135388161 hasConcept C2777871644 @default.
• W2135388161 hasConcept C2778541603 @default.
• W2135388161 hasConcept C2780256110 @default.

• next