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- W2135434517 abstract "In this study, well dispersed Cu@Co core–shell nanoparticles (NPs) on rGO surfaces were successfully synthesized via a one-step in situ procedure using methylamine borane (MeAB) as reductant under ambient conditions. The Cu@Co/rGO NPs exhibit superior catalytic activity than their alloy (CuCo/rGO) and graphene-free (Cu@Co) counterparts toward the hydrolytic dehydrogenation of ammonia borane (AB). Additionally, compared with the NPs reduced by AB, the as-synthesized Cu@Co/rGO NPs generated by the weaker reducing agent MeAB exhibit higher catalytic activities. Furthermore, the as-synthesized NPs exerted satisfactory catalytic activities and recycle stabilities for the hydrolysis of MeAB. Moreover, this general method indicates that MeAB can be used as both a potential hydrogen storage material and an efficient reductant which can be easily extended to the facile preparation of other rGO-supported metal NPs." @default.
- W2135434517 created "2016-06-24" @default.
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- W2135434517 date "2013-01-01" @default.
- W2135434517 modified "2023-10-16" @default.
- W2135434517 title "One-step synthesis of magnetically recyclable rGO supported Cu@Co core–shell nanoparticles: highly efficient catalysts for hydrolytic dehydrogenation of ammonia borane and methylamine borane" @default.
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- W2135434517 doi "https://doi.org/10.1039/c3nj00552f" @default.
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