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- W2135440384 abstract "The magnetic susceptibilities of single crystals of tetraethylammonium tetrachloronickelate(II) and bis-(N-isopropylsalicylaldiminato)nickel(II) have been measured over the temperature range 90–300°K. The anisotropy of the chloro-complex is characterized by a reversible discontinuity at ca. 218° associated with a small thermal hysteresis. The principal susceptibilities have been fitted to a theoretical spin–triplet model. The Cl–Ni–Cl angles calculated from the magnetic data of the chloro-compound above the transition temperature agree very well with those deduced from the room-temperature X-ray structure analysis. Orbital reduction factors and spin–orbit coupling coefficients for both complexes have been determined and are discussed." @default.
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- W2135440384 date "1969-01-01" @default.
- W2135440384 modified "2023-09-29" @default.
- W2135440384 title "Paramagnetic susceptibilities and anisotropies of nickel(<scp>II</scp>) ions in ‘tetrahedral’ environments. Part II. Covalency and distortion in tetraethylammonium tetrachloronickelate(<scp>II</scp>), and bis-(N-isopropyl-salicylaldiminato)nickel(<scp>II</scp>)" @default.
- W2135440384 doi "https://doi.org/10.1039/j19690001022" @default.
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