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• W2135646280 abstract "Abstract New synthetic routes to trifluoromethylated N‐heterocycles based on condensations of 2‐methoxy‐2‐methyl‐5‐(trifluoromethyl)furan‐3(2 H )‐one with bifunctional N‐nucleophiles are described. For the first time, trifluoromethyl‐containing pyrazoles, pyrazolines and isoxazolines bearing hydrazone or oxime groups could be obtained by a one‐pot strategy based on reactions of 5‐(trifluoromethyl)furan‐3(2 H )‐one with two equivalents of the corresponding hydrazines or hydroxylamine in the presence of an acid. The interaction of furan‐3(2 H )‐one with ureas proceeded under mild conditions to furnish 1 H ‐furo[2,3‐ d ]imidazol‐2(3 H )‐one derivatives in good yield. Further, a trifluoromethyl‐containing quinoxaline derivative was obtained by condensation of furan‐3(2 H )‐one with ortho ‐phenylenediamine." @default.
• W2135646280 created "2016-06-24" @default.
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• W2135646280 date "2015-07-02" @default.
• W2135646280 modified "2023-10-16" @default.
• W2135646280 title "A Convenient Approach to CF₃-Containing N-Heterocycles Based on 2-Methoxy-2-methyl-5-(trifluoromethyl)furan-3(2<i>H</i>)-one" @default.
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• W2135646280 doi "https://doi.org/10.1002/ejoc.201500737" @default.
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