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• W2135699334 abstract "IR and NMR spectral evidence indicates that α-diazosulfones, RSO2CHN2 (I), and α-diazoketones, RCOCHN2 (II), donate and accept protons in hydrogen bonding. The proton donor properties involve the methine proton as the donor site. The proton acceptor site is the sulfonyl group for α-diazosulfones and the carbonyl moiety for α-diazoketones. Using phenol as a donor molecule, OH stretching frequency shifts, Δν, have been measured for the α-diazosulfones Ia-Ig and the α-diazoketones IIa-IIf. Substituent effects on Δν values are modest for Ia-Ig but more pronounced for IIa-IIf. Compared with α-diazoketones, α-diazosulfones are stronger proton donors but weaker proton acceptors in hydrogen bonding." @default.
• W2135699334 created "2016-06-24" @default.
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• W2135699334 date "2010-09-02" @default.
• W2135699334 modified "2023-09-25" @default.
• W2135699334 title "Hydrogen bonding properties of α-Diazosulfones and α-Diazoketones" @default.
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• W2135699334 doi "https://doi.org/10.1002/recl.19700890709" @default.
• W2135699334 hasPublicationYear "2010" @default.
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