FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2135809158> ?p ?o ?g. }

• W2135809158 endingPage "146" @default.
• W2135809158 startingPage "136" @default.
• W2135809158 abstract "Abstract Iron- and/or aluminum-containing MFI zeolites were prepared via various routes, including isomorphous substitution followed by thermal activation and grafting reactions with molecular Fe or Al precursors over [Al]MFI and [Fe]MFI, respectively. The effect of the iron and aluminum content on the performance in benzene oxidation with nitrous oxide at 623 K was studied for a suite of isomorphously substituted zeolites. The activity increased with increasing iron and aluminum content. Steamed zeolites were more active than their calcined counterparts. The extent of coking deactivation increased with initial activity and tallies with a consecutive reaction mechanism in which phenol further reacts to products that cannot leave the zeolite micropores. A very small amount of iron is involved in the selective oxidation reaction. A strong correlation is observed between the initial rate of phenol formation and the intensity of the infrared band at 1635 cm −1 due to NO2 interacting with extraframework Fe O Al. On the other hand, nitrous oxide decomposition at higher temperatures is suggested to be mainly catalyzed by more clustered Fe species. Alternative preparation routes that use grafting of trimethylaluminum or iron chloride on otherwise inactive ferrosilicalite and aluminosilicalite, respectively, provide further support for the necessity of extraframework mixed iron–aluminum-oxo species. Steaming at high temperature is not only important for removal of the catalytically active metals from the zeolite framework, but also improves the formation of active sites. A case in point is the dispersion of Fe and Al in the micropores of silicalite-1, which renders an active, selective, and stable catalyst." @default.
• W2135809158 created "2016-06-24" @default.
• W2135809158 creator A5019315299 @default.
• W2135809158 creator A5027920218 @default.
• W2135809158 creator A5082285845 @default.
• W2135809158 date "2005-07-01" @default.
• W2135809158 modified "2023-09-27" @default.
• W2135809158 title "Selective oxidation of benzene to phenol with nitrous oxide over MFI zeolites2. On the effect of the iron and aluminum content and the preparation route" @default.
• W2135809158 cites W110221125 @default.
• W2135809158 cites W142619072 @default.
• W2135809158 cites W143342884 @default.
• W2135809158 cites W1512024383 @default.
• W2135809158 cites W174241045 @default.
• W2135809158 cites W186340877 @default.
• W2135809158 cites W1965756814 @default.
• W2135809158 cites W1968040991 @default.
• W2135809158 cites W1969240365 @default.
• W2135809158 cites W1983572885 @default.
• W2135809158 cites W1983630885 @default.
• W2135809158 cites W1992662197 @default.
• W2135809158 cites W1995633666 @default.
• W2135809158 cites W2003210763 @default.
• W2135809158 cites W2018180189 @default.
• W2135809158 cites W2018487721 @default.
• W2135809158 cites W2020761866 @default.
• W2135809158 cites W2029267942 @default.
• W2135809158 cites W2031635826 @default.
• W2135809158 cites W2036044786 @default.
• W2135809158 cites W2043165399 @default.
• W2135809158 cites W2046259804 @default.
• W2135809158 cites W2049534569 @default.
• W2135809158 cites W2050009077 @default.
• W2135809158 cites W2063133936 @default.
• W2135809158 cites W2063896065 @default.
• W2135809158 cites W2065207565 @default.
• W2135809158 cites W2065745217 @default.
• W2135809158 cites W2067618556 @default.
• W2135809158 cites W2071143819 @default.
• W2135809158 cites W2076402423 @default.
• W2135809158 cites W2077556786 @default.
• W2135809158 cites W2083796312 @default.
• W2135809158 cites W2111542576 @default.
• W2135809158 cites W2114249157 @default.
• W2135809158 cites W2162662175 @default.
• W2135809158 cites W2163214896 @default.
• W2135809158 cites W2168130998 @default.
• W2135809158 cites W2170228466 @default.
• W2135809158 cites W286507491 @default.
• W2135809158 cites W353377913 @default.
• W2135809158 cites W437822562 @default.
• W2135809158 cites W69040687 @default.
• W2135809158 doi "https://doi.org/10.1016/j.jcat.2005.04.008" @default.
• W2135809158 hasPublicationYear "2005" @default.
• W2135809158 type Work @default.
• W2135809158 sameAs 2135809158 @default.
• W2135809158 citedByCount "86" @default.
• W2135809158 countsByYear W21358091582012 @default.
• W2135809158 countsByYear W21358091582013 @default.
• W2135809158 countsByYear W21358091582014 @default.
• W2135809158 countsByYear W21358091582015 @default.
• W2135809158 countsByYear W21358091582016 @default.
• W2135809158 countsByYear W21358091582017 @default.
• W2135809158 countsByYear W21358091582018 @default.
• W2135809158 countsByYear W21358091582019 @default.
• W2135809158 countsByYear W21358091582020 @default.
• W2135809158 countsByYear W21358091582021 @default.
• W2135809158 countsByYear W21358091582022 @default.
• W2135809158 countsByYear W21358091582023 @default.
• W2135809158 crossrefType "journal-article" @default.
• W2135809158 hasAuthorship W2135809158A5019315299 @default.
• W2135809158 hasAuthorship W2135809158A5027920218 @default.
• W2135809158 hasAuthorship W2135809158A5082285845 @default.
• W2135809158 hasConcept C161790260 @default.
• W2135809158 hasConcept C178790620 @default.
• W2135809158 hasConcept C179104552 @default.
• W2135809158 hasConcept C185592680 @default.
• W2135809158 hasConcept C2777573673 @default.
• W2135809158 hasConcept C2777691172 @default.
• W2135809158 hasConcept C2777702071 @default.
• W2135809158 hasConcept C2779851234 @default.
• W2135809158 hasConcept C2910700394 @default.
• W2135809158 hasConcept C513153333 @default.
• W2135809158 hasConceptScore W2135809158C161790260 @default.
• W2135809158 hasConceptScore W2135809158C178790620 @default.
• W2135809158 hasConceptScore W2135809158C179104552 @default.
• W2135809158 hasConceptScore W2135809158C185592680 @default.
• W2135809158 hasConceptScore W2135809158C2777573673 @default.
• W2135809158 hasConceptScore W2135809158C2777691172 @default.
• W2135809158 hasConceptScore W2135809158C2777702071 @default.
• W2135809158 hasConceptScore W2135809158C2779851234 @default.
• W2135809158 hasConceptScore W2135809158C2910700394 @default.
• W2135809158 hasConceptScore W2135809158C513153333 @default.
• W2135809158 hasIssue "1" @default.
• W2135809158 hasLocation W21358091581 @default.
• W2135809158 hasOpenAccess W2135809158 @default.
• W2135809158 hasPrimaryLocation W21358091581 @default.
• W2135809158 hasRelatedWork W1577159406 @default.
• W2135809158 hasRelatedWork W1968040991 @default.

• next