FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2135846315> ?p ?o ?g. }

• W2135846315 endingPage "1912" @default.
• W2135846315 startingPage "1906" @default.
• W2135846315 abstract "Abstract The reaction of the complex [Mo(OTf)(η 3 ‐C 3 H 4 ‐Me‐2)(CO) 2 (phen)] ( 1 ) (OTf = trifluoromethylsulfonate; phen = 1,10‐phenanthroline) with tetrabutylammonium fluoride trihydrate afforded the fluoride complex [MoF(η 3 ‐C 3 H 4 ‐Me‐2)(CO) 2 (phen)] ( 2 ). The IR spectrum and the oxidation potential of 2 reflect the fact that its metal center is more electron‐rich than that of the chloro analogue [MoCl(η 3 ‐C 3 H 4 ‐Me‐2)(CO) 2 (phen)]. Compound 2 reacted with 1 affording the homobinuclear complex [{Mo(η 3 ‐C 3 H 4 ‐Me‐2)(CO) 2 (phen)} 2 (μ‐F)][OTf] ( 3 ), with a fluoride bridge. Compound 2 also reacts with the species generated in situ by triflate abstraction from [M(OTf)(CO) 3 (′NN′)] (M = Mn, Re; ′NN′ = 2,2′‐bipyridine (bipy), phen) using NaBAr′ 4 (Ar′ = 3,5‐bis(trifluoromethyl)phenyl), affording the heterobinuclear complexes [{Mo(η 3 ‐C 3 H 4 ‐Me‐2)(CO) 2 (phen)}(μ‐F){M(CO) 3 (′NN′)}][BAr′ 4 ] (M = Mn, ′NN′ = bipy ( 4 ); M = Re, ′NN′ = phen ( 5 )). All new compounds have been characterized by spectroscopic methods (IR and NMR) and, in the case of 1 , 2 , 3 , and 4 , also by means of X‐ray diffraction analysis." @default.
• W2135846315 created "2016-06-24" @default.
• W2135846315 creator A5001206198 @default.
• W2135846315 creator A5008593783 @default.
• W2135846315 creator A5016694882 @default.
• W2135846315 creator A5021962925 @default.
• W2135846315 creator A5043875277 @default.
• W2135846315 creator A5051492530 @default.
• W2135846315 creator A5066333054 @default.
• W2135846315 creator A5067288167 @default.
• W2135846315 creator A5067830382 @default.
• W2135846315 creator A5085176502 @default.
• W2135846315 date "2004-04-07" @default.
• W2135846315 modified "2023-10-12" @default.
• W2135846315 title "A Neutral Organometallic Fluoro Complex Can Be a Good Ligand" @default.
• W2135846315 cites W1966166320 @default.
• W2135846315 cites W1976708451 @default.
• W2135846315 cites W1978662243 @default.
• W2135846315 cites W1978901513 @default.
• W2135846315 cites W1985196286 @default.
• W2135846315 cites W1987639549 @default.
• W2135846315 cites W1988746075 @default.
• W2135846315 cites W1990664188 @default.
• W2135846315 cites W1993754785 @default.
• W2135846315 cites W1998806007 @default.
• W2135846315 cites W1999623416 @default.
• W2135846315 cites W2007608661 @default.
• W2135846315 cites W2014651821 @default.
• W2135846315 cites W2022636030 @default.
• W2135846315 cites W2049786401 @default.
• W2135846315 cites W2059233219 @default.
• W2135846315 cites W2069121032 @default.
• W2135846315 cites W2079175013 @default.
• W2135846315 cites W2082467664 @default.
• W2135846315 cites W2084126061 @default.
• W2135846315 cites W2084897334 @default.
• W2135846315 cites W2124680160 @default.
• W2135846315 cites W2136982777 @default.
• W2135846315 cites W2152833533 @default.
• W2135846315 cites W2159670464 @default.
• W2135846315 cites W2314585573 @default.
• W2135846315 cites W2321177444 @default.
• W2135846315 cites W2952701982 @default.
• W2135846315 cites W3136228498 @default.
• W2135846315 doi "https://doi.org/10.1002/chem.200305706" @default.
• W2135846315 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15079829" @default.
• W2135846315 hasPublicationYear "2004" @default.
• W2135846315 type Work @default.
• W2135846315 sameAs 2135846315 @default.
• W2135846315 citedByCount "11" @default.
• W2135846315 countsByYear W21358463152012 @default.
• W2135846315 countsByYear W21358463152015 @default.
• W2135846315 countsByYear W21358463152017 @default.
• W2135846315 crossrefType "journal-article" @default.
• W2135846315 hasAuthorship W2135846315A5001206198 @default.
• W2135846315 hasAuthorship W2135846315A5008593783 @default.
• W2135846315 hasAuthorship W2135846315A5016694882 @default.
• W2135846315 hasAuthorship W2135846315A5021962925 @default.
• W2135846315 hasAuthorship W2135846315A5043875277 @default.
• W2135846315 hasAuthorship W2135846315A5051492530 @default.
• W2135846315 hasAuthorship W2135846315A5066333054 @default.
• W2135846315 hasAuthorship W2135846315A5067288167 @default.
• W2135846315 hasAuthorship W2135846315A5067830382 @default.
• W2135846315 hasAuthorship W2135846315A5085176502 @default.
• W2135846315 hasConcept C115624301 @default.
• W2135846315 hasConcept C116569031 @default.
• W2135846315 hasConcept C155647269 @default.
• W2135846315 hasConcept C161790260 @default.
• W2135846315 hasConcept C170493617 @default.
• W2135846315 hasConcept C178790620 @default.
• W2135846315 hasConcept C179104552 @default.
• W2135846315 hasConcept C185592680 @default.
• W2135846315 hasConcept C21774173 @default.
• W2135846315 hasConcept C2776442012 @default.
• W2135846315 hasConcept C2779336533 @default.
• W2135846315 hasConcept C2780263894 @default.
• W2135846315 hasConcept C2780828025 @default.
• W2135846315 hasConcept C514695523 @default.
• W2135846315 hasConcept C544153396 @default.
• W2135846315 hasConcept C55493867 @default.
• W2135846315 hasConcept C71240020 @default.
• W2135846315 hasConcept C8010536 @default.
• W2135846315 hasConceptScore W2135846315C115624301 @default.
• W2135846315 hasConceptScore W2135846315C116569031 @default.
• W2135846315 hasConceptScore W2135846315C155647269 @default.
• W2135846315 hasConceptScore W2135846315C161790260 @default.
• W2135846315 hasConceptScore W2135846315C170493617 @default.
• W2135846315 hasConceptScore W2135846315C178790620 @default.
• W2135846315 hasConceptScore W2135846315C179104552 @default.
• W2135846315 hasConceptScore W2135846315C185592680 @default.
• W2135846315 hasConceptScore W2135846315C21774173 @default.
• W2135846315 hasConceptScore W2135846315C2776442012 @default.
• W2135846315 hasConceptScore W2135846315C2779336533 @default.
• W2135846315 hasConceptScore W2135846315C2780263894 @default.
• W2135846315 hasConceptScore W2135846315C2780828025 @default.
• W2135846315 hasConceptScore W2135846315C514695523 @default.
• W2135846315 hasConceptScore W2135846315C544153396 @default.
• W2135846315 hasConceptScore W2135846315C55493867 @default.

• next