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• W2135939056 startingPage "10485" @default.
• W2135939056 abstract "Optically active nitroalkenes 4 were synthesized via Henry reaction. Conjugate addition of vinylmagnesium bromide to 4 gave nitroalkane syn-5 while cyclopropanation with sulfur ylides or dibromocarbene afforded nitrocyclopropanes 8, 10 and 11 in a diastereoselective manner. These products were used to synthesize optically active β-amino acids 7 and 16 as well as cyclopropane γ-amino acids 19 and 20 by reduction of the nitro group and oxidative cleavage of the dioxolane substituent." @default.
• W2135939056 created "2016-06-24" @default.
• W2135939056 creator A5000986077 @default.
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• W2135939056 date "2002-12-01" @default.
• W2135939056 modified "2023-10-04" @default.
• W2135939056 title "Optically active nitroalkenes—synthesis, addition reactions and transformation into amino acids" @default.
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• W2135939056 doi "https://doi.org/10.1016/s0040-4020(02)01406-0" @default.
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