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- W2135963617 abstract "Regio- and stereoselectivities in conjugate reductions of steroidal 3-oxo-1,4-diene substrates, effected either directly by Fe(CO)5NaOHH2O in methanol solution or in two steps by NaBH4 reduction/Jones oxidation, depend on the substitution pattern of ring A. C(1) and C(2) methylated derivatives furnish Δ1 -products with 5β-stereochemistry, whereas C(4) methylated and unsubstituted steroids both afford Δ4-derivatives." @default.
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- W2135963617 date "1990-01-01" @default.
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- W2135963617 title "Regio- and stereoselective 1,4-reductions of methylated, cross-conjugated steroidal cyclohexadienones" @default.
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- W2135963617 doi "https://doi.org/10.1016/s0040-4039(00)97488-4" @default.
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