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• W2136004907 startingPage "1935" @default.
• W2136004907 abstract "Abstract The macrocycle in rotaxane 1 is preferentially hydrogen bonded to the succinamide station in the neutral form, but can be moved to the naphthalimide station by one‐electron reduction of the latter. The hydrogen bonding between the amide NH groups of the macrocycle and the CO groups in the binding stations in the thread was studied with IR spectroscopy in different solvents in both states. In addition, the solvent effect on the vibrational frequencies was analyzed; a correlation with the solvent acceptor number (AN) was observed. The conformational switching upon reduction could be detected by monitoring the hydrogen‐bond‐induced shifts of the ν (CO) frequencies of the CO groups of the succinamide and the reduced naphthalimide stations. The macrocycle was found to shield the encapsulated station from the solvent: wavenumbers of ν (CO) bands of the CO groups residing inside the macrocycle cavity remain unaffected by the solvent polarity." @default.
• W2136004907 created "2016-06-24" @default.
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• W2136004907 date "2008-02-11" @default.
• W2136004907 modified "2023-10-18" @default.
• W2136004907 title "Infrared Study of Intercomponent Interactions in a Switchable Hydrogen-Bonded Rotaxane" @default.
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• W2136004907 doi "https://doi.org/10.1002/chem.200701531" @default.
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