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- W2136084156 abstract "Abstract The kinetics of the reactions of substituted ethyl arylacetates with quinone methides and structurally related diethyl benzylidenemalonates have been studied in DMSO. The second‐order rate constants (lg k 2 ) correlated linearly with the electrophilicities E according to the linear free‐energy relationship lg k 2 = s N ( N + E ), allowing us to determine the nucleophilicity parameters N and s N for these anions. The nucleophilic reactivities of the carbanions vary from N = 27.5 for the parent compound to N = 20.0 for the 4‐nitro‐substituted derivative." @default.
- W2136084156 created "2016-06-24" @default.
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- W2136084156 date "2013-05-24" @default.
- W2136084156 modified "2023-10-16" @default.
- W2136084156 title "Quantification of the Nucleophilic Reactivities of Ethyl Arylacetate Anions" @default.
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- W2136084156 doi "https://doi.org/10.1002/ejoc.201300265" @default.
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