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- W2136105213 abstract "On présente un modèle de copolymérisation de l'éthylène et d'une α-oléfine qui décrit la consommation des monomères et la qualité du polymère produit, á savoir Mn, Mw, Mz, la distribution des masses moléculaires, les indices de branchement court et de doubles liaisons. Le modèle suppose qu'il existe plusieurs types de sites actifs (2 ou 3) et ne fait pas intervenir de limitation diffusionnelle. On l'applique á la copolymérisation en masse de l'éthylène et du butène-1 sous haute pression et haute température. Les paramètres sont identifiés grǎce á des essais en réacteur agité continu. A copolymerization model of ethylene and a α-olefin describing the monomer uptake and the quality of the polymer produced, namely Mn, Mw, Mz, the distribution of molecular weight, short branching index and double bonds, is presented. This model assumes the existence of several types of active sites (2 or 3) and do not involve any limiting diffusion. It is applied to ethylene and butene-1 bulk copolymerization at high pressure and high temperature. Parameters are identified with CSTR experiments." @default.
- W2136105213 created "2016-06-24" @default.
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- W2136105213 date "1991-06-01" @default.
- W2136105213 modified "2023-10-09" @default.
- W2136105213 title "Modéalisation de la copolyméarisation éathylégne α-oléafine par catalyse ziegler-natta" @default.
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- W2136105213 doi "https://doi.org/10.1002/cjce.5450690310" @default.
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