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• W2136127580 abstract "Tandem deoxygenation–neophyl-type radical rearrangement–electrophile trapping using xanthates from 7-azabenzonorbornadienes gives 3-exo-substituted 2-aza-5,6-benzonorbornenes, which in some cases undergo isomerisation to (aminomethyl)indenes. The starting xanthates are accessible in good yields and high enantiomeric ratios via asymmetric hydroboration of (aryne/pyrrole-derived) 7-azabenzonorbornadienes. Oxidation (using RuO4) and Birch reduction of the 2-aza-5,6-benzonorbornenes provide access to substituted pyrrolidines and tetrahydroindenes, respectively." @default.
• W2136127580 created "2016-06-24" @default.
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• W2136127580 date "2008-10-24" @default.
• W2136127580 modified "2023-09-30" @default.
• W2136127580 title "Radical cascades using enantioenriched 7-azabenzonorbornenes and their applications in synthesis" @default.
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• W2136127580 doi "https://doi.org/10.3762/bjoc.4.38" @default.
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