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- W2136127792 abstract "The electrochemical behavior of the Pb 2+ /Pb(Hg) system in aqueous and aqueous ethylene glycol solutions is studied in the temperature range of 20.0 to 50.0 °C by means of current reversal chronopotentiometry. It is shown that the reduction of Pb 2+ ion is reversible and that kinetic or catalytic complications are not present. The value of dE 1/2 /dT is −0.6 mV/deg in the aqueous solution and −0.5 mV/deg in the solution with 56% (w/w) or higher concentrations of the organic solvent. In the above concentration range of ethylene glycol the activation energies of diffusion and viscosity vary from 4.3 × 10 3 to 7.2 × 10 3 cal mol −1 and from 3.7 × 10 3 to 6.7 × 10 3 cal mol −1 , respectively. For all solutions the solvodynamic mean radius of the diffusing species remains constant within the experimental error, suggesting that the diffusing species is always the hydrated Pb 2+ ion." @default.
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- W2136127792 date "1979-07-15" @default.
- W2136127792 modified "2023-09-24" @default.
- W2136127792 title "Electrochemical studies of the Pb2+/Pb(Hg) system in aqueous and aqueous ethylene glycol solutions" @default.
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- W2136127792 doi "https://doi.org/10.1139/v79-287" @default.
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