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- W2136147368 abstract "The crystal structure of N-methyl-1,3-benzothiazole-2(3H)-selone (mbts) has been studied in order to estimate the changes in the molecular geometry of the mbts ligand upon coordination. Hypervalent complexes of mbts with Te II and I I have been studied by us previously. A significant elongation of the Se=C bond [from 1.817 (7) in mbts to 1.85-1.88 A in the complexes] was found, but there were no significant changes in the other geometric parameters of the ligand. The only other bond-length decrease of note was for SeC-NMe [from 1.35 (1) in mbts to 1.32-1.34 A in the complexes]. Thus, only the amino group takes part in electron redistribution upon coordination." @default.
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- W2136147368 date "2010-08-03" @default.
- W2136147368 modified "2023-09-25" @default.
- W2136147368 title "ChemInform Abstract: N-Methylbenzothiazole-2(3H)-selone, C8H7NSSe." @default.
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- W2136147368 doi "https://doi.org/10.1002/chin.199741042" @default.
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