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• W2136240764 endingPage "14885" @default.
• W2136240764 startingPage "14876" @default.
• W2136240764 abstract "Abstract The comprehensive study reported herein provides compelling evidence that anion templates are the main driving force in the formation of two novel nanoscale lanthanide hydroxide clusters, {Gd 38 (ClO 4 ) 6 } ( 1 ) and {Gd 48 Cl 2 (NO 3 )} ( 2 ), characterized by single‐crystal X‐ray crystallography, infrared spectroscopy, and magnetic measurements. {Gd 38 (ClO 4 ) 6 }, encapsulating six ClO 4 − ions, features a cage core composed of twelve vertex‐sharing {Gd 4 } tetrahedrons and one Gd⋅⋅⋅Gd pillar. When Cl − and NO 3 − were incorporated in the reaction instead of ClO 4 − , {Gd 48 Cl 2 (NO 3 )} is obtained with a barrel shape constituted by twelve vertex‐sharing {Gd 4 } tetrahedrons and six {Gd 5 } pyramids. What is more, the cage‐like {Gd 38 } can be dynamically converted into the barrel‐shaped {Gd 48 } upon Cl − and NO 3 − stimulus. To our knowledge, it is the first time that the linear M‐O‐M′ fashion and the unique μ 8 ‐ClO 4 − mode have been crystallized in pure lanthanide complex, and complex 2 represents the largest gadolinium cluster. Both of the complexes display large magnetocaloric effect in units of J kg −1 K −1 and mJ cm −3 K −1 on account of the weak antiferromagnetic exchange, the high N Gd / M W ratio (magnetic density), and the relatively compact crystal lattice (mass density)." @default.
• W2136240764 created "2016-06-24" @default.
• W2136240764 creator A5002340076 @default.
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• W2136240764 creator A5059735887 @default.
• W2136240764 creator A5062973942 @default.
• W2136240764 creator A5071764319 @default.
• W2136240764 date "2013-09-17" @default.
• W2136240764 modified "2023-10-18" @default.
• W2136240764 title "Anion-Templated Assembly and Magnetocaloric Properties of a Nanoscale {Gd₃₈} Cage versus a {Gd₄₈} Barrel" @default.
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