FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2136281010> ?p ?o ?g. }

• W2136281010 endingPage "425" @default.
• W2136281010 startingPage "415" @default.
• W2136281010 abstract "R2NPNR (RSi(CH3)3) reagiert mit Alkylhalogeniden wie CCl4, i-C3H7Br und C2H5J unter 1,1-Addition am Phosphor zu Iminophosphoranen R2NP(X)R′ NR (3–5). Lewis-acide Halogenide des Siliciums und Zinns setzen sich mit dem Iminophosphin über ein intermediäres 1,2-Additionsprodukt unter Abspaltung von Trimethylsilylhalogenid bzw. Zinndichlorid zu Diazaphosphasilacyclobutanen 6 und 7 bzw. dem. Iminodichlorphosphoran 10 um. Bei der Reaktion des Germaniumtetrachlorids wird das entsprechende 1,2-Additionsprodukt 8 erhalten. Halogene überführen das Iminophosphin quantitativ in die entsprechenden Iminophosphorane R2NP(X2)NR (XF, Cl, Br, J) (10–13). Das Brom- und das Jodderivat zerfallen bereits unterhalb 100°C in Halogensilan und das entsprechende Diazadiphosphetidin-diimid (RNP(X)NR)2 (XBr, J) (14–15). Die IR- und NMR-Spektren (1H, 29Si 31)P) werden kurz diskutiert. Reaction of an N-silylated Iminophosphine (Phospha(III)azene) with Halogen Compounds of Elements of Main Groups IV and VII R2N-PNR (RSi(CH3)3) reacts with alkyl halides such as CCl4, i-C3H7Br, and C2H5I to give the 1,1-addition products at phosphorus, the iminophosphoranes R2NP(X)R′ NR (3–5). Reaction of the acidic halides of silicon and tin with the iminophosphine results in the formation of the 1,2-addition products as intermediates; subsequent elimination of trimethylsilylhalide and tin dichloride, respectively, yields the diazaphosphasilacyclobutanes 6 and 7 and the iminodichlorophosphorane 10, respectively. With germanium tetrachloride, the 1,2-addition product 8 is obtained. Halogens react with the iminophosphine to produce the corresponding iminophosphoranes R2NP(X2)NR (XF, Cl, Br, I) (10–13) in quantitative yields. The bromo and iodo derivatives are decomposed below 100°C and eliminate silicon halide to form the diazadiphosphetidines (RNP(X)NR)2 (XBr, I) (14–15). The i. r. and n. m. r. spectra (1H. 29Si. 31P) are briefly discussed." @default.
• W2136281010 created "2016-06-24" @default.
• W2136281010 creator A5009705377 @default.
• W2136281010 creator A5025875408 @default.
• W2136281010 date "1976-02-01" @default.
• W2136281010 modified "2023-10-09" @default.
• W2136281010 title "Reaktionen eines <i>N</i> ‐Silylierten Iminophosphins (Phospha(III)azens) mit Halogenverbindungen der IV. und VII. Hauptgruppe ¹⁾" @default.
• W2136281010 cites W1969457332 @default.
• W2136281010 cites W1982058423 @default.
• W2136281010 cites W1984507075 @default.
• W2136281010 cites W1999104804 @default.
• W2136281010 cites W2036888339 @default.
• W2136281010 cites W2040277524 @default.
• W2136281010 cites W2059333272 @default.
• W2136281010 cites W2081078224 @default.
• W2136281010 cites W2083015311 @default.
• W2136281010 cites W2091413215 @default.
• W2136281010 cites W2140243019 @default.
• W2136281010 doi "https://doi.org/10.1002/cber.19761090202" @default.
• W2136281010 hasPublicationYear "1976" @default.
• W2136281010 type Work @default.
• W2136281010 sameAs 2136281010 @default.
• W2136281010 citedByCount "48" @default.
• W2136281010 countsByYear W21362810102016 @default.
• W2136281010 countsByYear W21362810102017 @default.
• W2136281010 crossrefType "journal-article" @default.
• W2136281010 hasAuthorship W2136281010A5009705377 @default.
• W2136281010 hasAuthorship W2136281010A5025875408 @default.
• W2136281010 hasConcept C155647269 @default.
• W2136281010 hasConcept C171560689 @default.
• W2136281010 hasConcept C178790620 @default.
• W2136281010 hasConcept C185592680 @default.
• W2136281010 hasConcept C2780263894 @default.
• W2136281010 hasConcept C46062151 @default.
• W2136281010 hasConcept C525849907 @default.
• W2136281010 hasConceptScore W2136281010C155647269 @default.
• W2136281010 hasConceptScore W2136281010C171560689 @default.
• W2136281010 hasConceptScore W2136281010C178790620 @default.
• W2136281010 hasConceptScore W2136281010C185592680 @default.
• W2136281010 hasConceptScore W2136281010C2780263894 @default.
• W2136281010 hasConceptScore W2136281010C46062151 @default.
• W2136281010 hasConceptScore W2136281010C525849907 @default.
• W2136281010 hasIssue "2" @default.
• W2136281010 hasLocation W21362810101 @default.
• W2136281010 hasOpenAccess W2136281010 @default.
• W2136281010 hasPrimaryLocation W21362810101 @default.
• W2136281010 hasRelatedWork W1905210583 @default.
• W2136281010 hasRelatedWork W1979644962 @default.
• W2136281010 hasRelatedWork W2003901887 @default.
• W2136281010 hasRelatedWork W2006032314 @default.
• W2136281010 hasRelatedWork W2022836528 @default.
• W2136281010 hasRelatedWork W2077695240 @default.
• W2136281010 hasRelatedWork W2105813659 @default.
• W2136281010 hasRelatedWork W2116777351 @default.
• W2136281010 hasRelatedWork W2154956604 @default.
• W2136281010 hasRelatedWork W2949469678 @default.
• W2136281010 hasVolume "109" @default.
• W2136281010 isParatext "false" @default.
• W2136281010 isRetracted "false" @default.
• W2136281010 magId "2136281010" @default.
• W2136281010 workType "article" @default.