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- W2136335035 abstract "Treatment of [Rh(1,5-C8H12)(MeCN)2]+BF4– with ButNC, PriNC, or p-MeOC6H4NC affords [Rh(RNC)4]+BF4–(R = But, Pri, or p-MeOC6H4). Addition of l2, Mel, Etl, Prnl, Bunl, PhCH2l, or PhCH2Cl to [Rh(ButNC)4]+BF4– affords the octahedral RhIII species [Rh(ButNC)4XY]+BF4–. Trimethyloxonium and nitrosyl tetrafluoroborate react with [Rh(ButNC)4]+BF4– to form respectively compounds containing the dications [Rh(ButNC)4Me]2+ and [Rh(ButNC)4NO]2+. Dimethyl- and diethyl-amine, and the primary amines ethyl-, n-propyl-, isopropyl-, n-butyl-, isobutyl-, and cyclohexyl-amine react rapidly with [Rh(ButNC)4]+BF4– to form the carbene or amidinium derivatives [Rh(ButNC)3C(NHBut)NR1R2]+BF4–(R1= R2= Me or Et; R1= H, R2= Et, Prn, Pri, Bun, Bui, or C6H11). The structure of these compounds is discussed together with their isomerisation by C–N rotation. The carbene complexes undergo oxidative-addition reactions with l2, Mel, and PhCH2l to form [Rh(ButNC)3{C(NHBut)-NHR}XY]+BF4–." @default.
- W2136335035 created "2016-06-24" @default.
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- W2136335035 date "1972-01-01" @default.
- W2136335035 modified "2023-10-14" @default.
- W2136335035 title "Cationic transition-metal complexes. Part III. Synthesis and reactions of tetrakis(isocyanide)rhodium tetrafluoroborate complexes" @default.
- W2136335035 doi "https://doi.org/10.1039/dt9720001303" @default.
- W2136335035 hasPublicationYear "1972" @default.
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