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• W2136335344 abstract "The reaction of [26]hexaphyrin with triethylamine in the presence of BF3 ⋅OEt2 and O2 furnished a diastereomeric mixture of a diethylamine-bearing [28]hexaphyrin as a rare example of a Möbius aromatic metal-free expanded porphyrin. The Möbius aromaticity of these molecules is large, as indicated by their large diatropic ring currents, which are even preserved at 100 °C, owing to their internally multiply bridged robust structure with a smooth conjugation network. These molecules were reduced with NaBH4 to give an antiaromatic [28]hexaphyrin, and were oxidized with MnO2 to give aromatic [26]hexaphyrins, both through a Möbius-to-Hückel topology switch induced by a CN bond cleavage." @default.
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• W2136335344 date "2015-02-04" @default.
• W2136335344 modified "2023-10-01" @default.
• W2136335344 title "A Möbius Aromatic [28]Hexaphyrin Bearing a Diethylamine Group: A Rigid but Smooth Conjugation Circuit" @default.
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• W2136335344 doi "https://doi.org/10.1002/anie.201500099" @default.
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