FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2136500314> ?p ?o ?g. }

• W2136500314 endingPage "5824" @default.
• W2136500314 startingPage "5815" @default.
• W2136500314 abstract "This paper is devoted to the investigation of the phototransformation mechanisms of PVK exposed to long-wavelength radiations (λ > 300 nm) in the absence and in the presence of oxygen. PVK irradiated as thin films was analyzed by fluorescence, UV−vis, and IR spectroscopies. The photoproducts formed were identified by postirradiation treatments including chemical derivatization reactions and HPLC analysis. The cross-linking was evaluated by gel fraction measurements. PVK is known to give an intense excimer fluorescence and no monomer fluorescence. The phototransformations provoked by light absorption are shown to lead to a dramatic decrease of this fluorescence which can be correlated with the modification of the chemical structure of the macromolecules. The decrease of fluorescence is the result of the diminution of the local mobility of the macromolecular chains resulting from cross-linking reactions provoked by the recombination of the several radicalar species. A general mechanism accounting for the phototransformation of PVK in the presence and in the absence of oxygen is proposed." @default.
• W2136500314 created "2016-06-24" @default.
• W2136500314 creator A5008674676 @default.
• W2136500314 creator A5027013898 @default.
• W2136500314 creator A5027488039 @default.
• W2136500314 creator A5032423148 @default.
• W2136500314 creator A5039587487 @default.
• W2136500314 date "2003-06-27" @default.
• W2136500314 modified "2023-10-18" @default.
• W2136500314 title "Investigation of the Photophysical Processes and Photochemical Reactions Involved in PVK Films Irradiated at λ > 300 nm" @default.
• W2136500314 cites W1964550661 @default.
• W2136500314 cites W1978088833 @default.
• W2136500314 cites W1987708857 @default.
• W2136500314 cites W1990519651 @default.
• W2136500314 cites W2004295237 @default.
• W2136500314 cites W2007578287 @default.
• W2136500314 cites W2012070557 @default.
• W2136500314 cites W2015215314 @default.
• W2136500314 cites W2024484455 @default.
• W2136500314 cites W2038150180 @default.
• W2136500314 cites W2039146939 @default.
• W2136500314 cites W2039253874 @default.
• W2136500314 cites W2045812470 @default.
• W2136500314 cites W2053503539 @default.
• W2136500314 cites W2057006751 @default.
• W2136500314 cites W2065733256 @default.
• W2136500314 cites W2072724368 @default.
• W2136500314 cites W2075661205 @default.
• W2136500314 cites W2082449846 @default.
• W2136500314 cites W2086029883 @default.
• W2136500314 cites W2093288770 @default.
• W2136500314 cites W2136476987 @default.
• W2136500314 cites W2154004326 @default.
• W2136500314 cites W2525483277 @default.
• W2136500314 doi "https://doi.org/10.1021/ma034354x" @default.
• W2136500314 hasPublicationYear "2003" @default.
• W2136500314 type Work @default.
• W2136500314 sameAs 2136500314 @default.
• W2136500314 citedByCount "49" @default.
• W2136500314 countsByYear W21365003142012 @default.
• W2136500314 countsByYear W21365003142013 @default.
• W2136500314 countsByYear W21365003142014 @default.
• W2136500314 countsByYear W21365003142015 @default.
• W2136500314 countsByYear W21365003142016 @default.
• W2136500314 countsByYear W21365003142017 @default.
• W2136500314 countsByYear W21365003142018 @default.
• W2136500314 countsByYear W21365003142019 @default.
• W2136500314 countsByYear W21365003142021 @default.
• W2136500314 countsByYear W21365003142022 @default.
• W2136500314 countsByYear W21365003142023 @default.
• W2136500314 crossrefType "journal-article" @default.
• W2136500314 hasAuthorship W2136500314A5008674676 @default.
• W2136500314 hasAuthorship W2136500314A5027013898 @default.
• W2136500314 hasAuthorship W2136500314A5027488039 @default.
• W2136500314 hasAuthorship W2136500314A5032423148 @default.
• W2136500314 hasAuthorship W2136500314A5039587487 @default.
• W2136500314 hasConcept C111337013 @default.
• W2136500314 hasConcept C120665830 @default.
• W2136500314 hasConcept C121332964 @default.
• W2136500314 hasConcept C125287762 @default.
• W2136500314 hasConcept C159985019 @default.
• W2136500314 hasConcept C166940927 @default.
• W2136500314 hasConcept C178790620 @default.
• W2136500314 hasConcept C179998833 @default.
• W2136500314 hasConcept C185544564 @default.
• W2136500314 hasConcept C185592680 @default.
• W2136500314 hasConcept C192562407 @default.
• W2136500314 hasConcept C204389451 @default.
• W2136500314 hasConcept C2776923573 @default.
• W2136500314 hasConcept C521977710 @default.
• W2136500314 hasConcept C540031477 @default.
• W2136500314 hasConcept C55493867 @default.
• W2136500314 hasConcept C74561354 @default.
• W2136500314 hasConcept C75473681 @default.
• W2136500314 hasConcept C91881484 @default.
• W2136500314 hasConceptScore W2136500314C111337013 @default.
• W2136500314 hasConceptScore W2136500314C120665830 @default.
• W2136500314 hasConceptScore W2136500314C121332964 @default.
• W2136500314 hasConceptScore W2136500314C125287762 @default.
• W2136500314 hasConceptScore W2136500314C159985019 @default.
• W2136500314 hasConceptScore W2136500314C166940927 @default.
• W2136500314 hasConceptScore W2136500314C178790620 @default.
• W2136500314 hasConceptScore W2136500314C179998833 @default.
• W2136500314 hasConceptScore W2136500314C185544564 @default.
• W2136500314 hasConceptScore W2136500314C185592680 @default.
• W2136500314 hasConceptScore W2136500314C192562407 @default.
• W2136500314 hasConceptScore W2136500314C204389451 @default.
• W2136500314 hasConceptScore W2136500314C2776923573 @default.
• W2136500314 hasConceptScore W2136500314C521977710 @default.
• W2136500314 hasConceptScore W2136500314C540031477 @default.
• W2136500314 hasConceptScore W2136500314C55493867 @default.
• W2136500314 hasConceptScore W2136500314C74561354 @default.
• W2136500314 hasConceptScore W2136500314C75473681 @default.
• W2136500314 hasConceptScore W2136500314C91881484 @default.
• W2136500314 hasIssue "15" @default.
• W2136500314 hasLocation W21365003141 @default.
• W2136500314 hasLocation W21365003142 @default.
• W2136500314 hasLocation W21365003143 @default.

• next