FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2136635741> ?p ?o ?g. }

• W2136635741 endingPage "217" @default.
• W2136635741 startingPage "208" @default.
• W2136635741 abstract "Reactions of the molybdates Na(2)MoO4.2 H2O and (nBu(4)N)2[Mo2O7] with [[Ru(arene)Cl(2)](2)] (arene=C(6)H5CH3, 1,3,5-C6H3(CH3)(3), 1,2,4,5-C6H2(CH3)4) in water or organic solvents led to formation of the triple-cubane organometallic oxides [[Ru(eta(6)-arene)](4)Mo4O16], whose crystal and molecular structures were determined. Refluxing triple cubane [[Ru(eta(6)-C6H5CH3)](4)Mo4O16] in methanol caused partial isomerization to the windmill form. The two isomers of [[Ru(eta(6)-C6H5CH3)](4)Mo4O16] were characterized by Raman and Mo K-edge X-ray absorption spectroscopy (XAS), both in the solid-state and in solution. This triple-cubane isomer was also used as a spectroscopic model to account for isomerization of the p-cymene windmill [[Ru(eta(6)-1,4-CH3C6H4CH(CH3)2)](4)Mo4O16] in solution. Using both Raman and XAS techniques, we were then able to determine the ratio between the windmill and triple-cubane isomers in dichloromethane and in chloroform. Density functional calculations on [[Ru(eta(6)-arene)](4)Mo4O16] (arene=C6H6, C6H5CH3, 1,3,5-C6H3(CH3)3, 1,4-CH3C6H4CH(CH3)2, C6(CH3)6) suggest that the windmill form is intrinsically more stable, provided the complexes are assumed to be isolated. Intramolecular electrostatic interactions and steric bulk induced by substituted arenes were found to modulate but not to reverse the energy difference between the isomers. The stability of the triple-cubane isomers should therefore be accounted for by effects of the surroundings that induce a shift in the energy balance between both forms." @default.
• W2136635741 created "2016-06-24" @default.
• W2136635741 creator A5004134184 @default.
• W2136635741 creator A5014983483 @default.
• W2136635741 creator A5020932811 @default.
• W2136635741 creator A5039949771 @default.
• W2136635741 creator A5042969714 @default.
• W2136635741 creator A5045181426 @default.
• W2136635741 creator A5046874077 @default.
• W2136635741 creator A5054438179 @default.
• W2136635741 creator A5065364449 @default.
• W2136635741 creator A5071768046 @default.
• W2136635741 creator A5078873406 @default.
• W2136635741 date "2003-12-19" @default.
• W2136635741 modified "2023-10-18" @default.
• W2136635741 title "Framework Fluxionality of Organometallic Oxides: Synthesis, Crystal Structure, EXAFS, and DFT Studies on[{Ru(η6-arene)}4Mo4O16] Complexes" @default.
• W2136635741 cites W1532684710 @default.
• W2136635741 cites W1536468465 @default.
• W2136635741 cites W1826233890 @default.
• W2136635741 cites W1954279716 @default.
• W2136635741 cites W1967037822 @default.
• W2136635741 cites W1977785466 @default.
• W2136635741 cites W1989059101 @default.
• W2136635741 cites W1995647974 @default.
• W2136635741 cites W1995729718 @default.
• W2136635741 cites W2000658010 @default.
• W2136635741 cites W2007185365 @default.
• W2136635741 cites W2016079918 @default.
• W2136635741 cites W2017346763 @default.
• W2136635741 cites W2017714830 @default.
• W2136635741 cites W2020114693 @default.
• W2136635741 cites W2021426228 @default.
• W2136635741 cites W2023692073 @default.
• W2136635741 cites W2023695570 @default.
• W2136635741 cites W2026673349 @default.
• W2136635741 cites W2026915320 @default.
• W2136635741 cites W2027687551 @default.
• W2136635741 cites W2027731038 @default.
• W2136635741 cites W2030687437 @default.
• W2136635741 cites W2031250378 @default.
• W2136635741 cites W2038533471 @default.
• W2136635741 cites W2038573072 @default.
• W2136635741 cites W2040891489 @default.
• W2136635741 cites W2044143378 @default.
• W2136635741 cites W2047772510 @default.
• W2136635741 cites W2047897739 @default.
• W2136635741 cites W2055230539 @default.
• W2136635741 cites W2070405144 @default.
• W2136635741 cites W2072351869 @default.
• W2136635741 cites W2073815491 @default.
• W2136635741 cites W2086957099 @default.
• W2136635741 cites W2087408259 @default.
• W2136635741 cites W2093706363 @default.
• W2136635741 cites W2101748147 @default.
• W2136635741 cites W2106220271 @default.
• W2136635741 cites W2129358463 @default.
• W2136635741 cites W2130794870 @default.
• W2136635741 cites W2148066840 @default.
• W2136635741 cites W2949706303 @default.
• W2136635741 doi "https://doi.org/10.1002/chem.200305396" @default.
• W2136635741 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14695565" @default.
• W2136635741 hasPublicationYear "2003" @default.
• W2136635741 type Work @default.
• W2136635741 sameAs 2136635741 @default.
• W2136635741 citedByCount "43" @default.
• W2136635741 countsByYear W21366357412012 @default.
• W2136635741 countsByYear W21366357412013 @default.
• W2136635741 countsByYear W21366357412014 @default.
• W2136635741 countsByYear W21366357412015 @default.
• W2136635741 countsByYear W21366357412016 @default.
• W2136635741 countsByYear W21366357412017 @default.
• W2136635741 countsByYear W21366357412018 @default.
• W2136635741 countsByYear W21366357412019 @default.
• W2136635741 countsByYear W21366357412021 @default.
• W2136635741 countsByYear W21366357412022 @default.
• W2136635741 countsByYear W21366357412023 @default.
• W2136635741 crossrefType "journal-article" @default.
• W2136635741 hasAuthorship W2136635741A5004134184 @default.
• W2136635741 hasAuthorship W2136635741A5014983483 @default.
• W2136635741 hasAuthorship W2136635741A5020932811 @default.
• W2136635741 hasAuthorship W2136635741A5039949771 @default.
• W2136635741 hasAuthorship W2136635741A5042969714 @default.
• W2136635741 hasAuthorship W2136635741A5045181426 @default.
• W2136635741 hasAuthorship W2136635741A5046874077 @default.
• W2136635741 hasAuthorship W2136635741A5054438179 @default.
• W2136635741 hasAuthorship W2136635741A5065364449 @default.
• W2136635741 hasAuthorship W2136635741A5071768046 @default.
• W2136635741 hasAuthorship W2136635741A5078873406 @default.
• W2136635741 hasConcept C115624301 @default.
• W2136635741 hasConcept C118629725 @default.
• W2136635741 hasConcept C119824511 @default.
• W2136635741 hasConcept C120665830 @default.
• W2136635741 hasConcept C121332964 @default.
• W2136635741 hasConcept C126661725 @default.
• W2136635741 hasConcept C145148216 @default.
• W2136635741 hasConcept C147597530 @default.
• W2136635741 hasConcept C152365726 @default.
• W2136635741 hasConcept C161790260 @default.

• next