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- W2136694611 abstract "Rearrangement enablers: α-Alkoxy allenes undergo regioselective oxidative migration to give α′-alkoxy enones in good to excellent yields (see scheme; Bn=benzyl, mCPBA=m-chloroperbenzoic acid). The influence of substituents on the allene, at C1, and at the oxygen atom has been examined. In addition, an oxidative cascade delivers α′-alkoxy oxiranyl ketones through diepoxidation. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2136694611 date "2010-08-26" @default.
- W2136694611 modified "2023-10-18" @default.
- W2136694611 title "Oxidation of α-Alkoxy Allenes into α′-Alkoxy Enones" @default.
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- W2136694611 doi "https://doi.org/10.1002/chem.201000914" @default.
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