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• W2136791808 startingPage "110" @default.
• W2136791808 abstract "A series of water-soluble platinum(II) complexes containing bidentate imino pyridine ligands L of the general formula LPtX 2 (X=Cl or Me) have been prepared. The dichloro complexes are very stable in water or dimethyl sulfoxide (DMSO), even at elevated temperatures, whereas the dimethyl complexes are less stable in these strongly polar solvents. In DMSO, an equilibrium between the complex LPtMe 2 and (DMSO) 2 PtMe 2 is observed, whereas in water decomposition is observed within 1 day at room temperature. A series of water-soluble platinum(II) dichloro and dialkyl complexes have been prepared. Whereas the dichloro complexes are stable in strongly polar solvents such as water or dimethyl sulfoxide, the dialkyl complexes decompose slowly, typically within a day at room temperature. These findings may have important ramifications for their application in catalysis." @default.
• W2136791808 created "2016-06-24" @default.
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• W2136791808 date "2003-08-01" @default.
• W2136791808 modified "2023-09-24" @default.
• W2136791808 title "Synthesis and reactivity of water-soluble platinum(II) complexes containing nitrogen ligands" @default.
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• W2136791808 doi "https://doi.org/10.1016/s0022-328x(03)00540-0" @default.
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