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• W2136857331 endingPage "2965" @default.
• W2136857331 startingPage "2960" @default.
• W2136857331 abstract "A highly effective visible light-promoted “radical-type” coupling of N-heteroarenes with aryldiazonium salts in water has been developed. The reaction proceeds at room temperature with [Ru(bpy)3]Cl2⋅6 H2O as a photosensitizer and a commercial household light bulb as a light source. Pyridine and a variety of substituted pyridines are effective substrates under these reaction conditions, and only monosubstituted products are formed with different regioselectivities. Using aqueous formic acid as solvent, an array of xanthenes, thiazole, pyrazine, and pyridazine are compatible with this new arylation approach. The broad substrate scope, mild reaction conditions, and use of water as reaction solvent make this procedure a practical and environmentally friendly method for the synthesis of compounds containing aryl-heteroaryl motifs." @default.
• W2136857331 created "2016-06-24" @default.
• W2136857331 creator A5010039029 @default.
• W2136857331 creator A5019405663 @default.
• W2136857331 creator A5049466493 @default.
• W2136857331 creator A5067926884 @default.
• W2136857331 creator A5077803220 @default.
• W2136857331 creator A5078527783 @default.
• W2136857331 date "2014-02-05" @default.
• W2136857331 modified "2023-10-14" @default.
• W2136857331 title "Direct Arylation of N-Heteroarenes with Aryldiazonium Salts by Photoredox Catalysis in Water" @default.
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