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- W2136934211 abstract "Some results obtained in the stereospecific polymerization of 2-tert-butyl-1,3-butadiene are reported. The catalysts employed were prepared from TiCl4 and aluminum alkyls or soluble aluminum hydride derivatives. Polymers thus obtained were crystalline with a melting point of 106°C. and soluble in common solvents. X-ray investigation shows the polymer to have a helical chain structure built on 11 monomeric units with cis configuration, distributed on three turns. The identity period along the chain axis is 15.3 A. A comparison of the infrared spectra of the crystalline and amorphous polymers is given. Attempts to obtain a crystalline 1,4-trans polymer failed; this is in accord with the lower stability of such a configuration due to steric repulsion of the bulky group." @default.
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- W2136934211 date "1964-10-01" @default.
- W2136934211 modified "2023-10-16" @default.
- W2136934211 title "Stereospecific polymerization of 2-substituted-1,3-butadienes. I. Crystalline polymers of 2-tert-butyl-1,3-butadiene" @default.
- W2136934211 doi "https://doi.org/10.1002/pol.1964.100021001" @default.
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