Matches in SemOpenAlex for { <https://semopenalex.org/work/W2136964613> ?p ?o ?g. }
- W2136964613 abstract "We present a study of microphase separation induced by competitive hydrogen bonding in A-b-B/C diblock copolymer/homopolymer complexes where the diblock copolymer A-b-B is immiscible and the homopolymer C can interact unequally with both A and B blocks through hydrogen bonding. A model system containing poly(2-vinyl pyridine)-block-poly(methyl methacrylate) (P2VP-b-PMMA) and poly(4-vinyl phenol) (PVPh) in tetrahydrofuran was investigated. In these self-assembled complexes, microphase separation takes place due to the disparity in intermolecular interactions. Specifically, PVPh and P2VP blocks interact strongly to form complex, whereas PVPh and PMMA blocks interact weakly. The hydrogen bonding interactions were revealed by infrared spectroscopy and analyzed in terms of the difference in interassociation constants (K), i.e., interaction parameters of each blocks of the block copolymer to the homopolymer and according to the random phase approximation. The phase behavior of the complexes was investigated with small-angle x-ray scattering and transmission electron microscopy. A series of morphologies including lamellae, hexagonal cylinders, wormlike microdomains, and hierarchical structures was documented as a function of the copolymer concentration. Moreover, we outlined how hydrogen bonding determines the self-assembly and causes morphological transitions in different A-b-B/C diblock copolymer/homopolymer systems with respect to the K values." @default.
- W2136964613 created "2016-06-24" @default.
- W2136964613 creator A5030290474 @default.
- W2136964613 creator A5040102566 @default.
- W2136964613 creator A5065669622 @default.
- W2136964613 date "2009-12-04" @default.
- W2136964613 modified "2023-09-26" @default.
- W2136964613 title "Microphase separation through competitive hydrogen bonding in self-assembled A-b-B/C diblock copolymer/homopolymer complexes" @default.
- W2136964613 cites W1479725456 @default.
- W2136964613 cites W1966166072 @default.
- W2136964613 cites W1969662382 @default.
- W2136964613 cites W1973030654 @default.
- W2136964613 cites W1974487446 @default.
- W2136964613 cites W1975899172 @default.
- W2136964613 cites W1976240549 @default.
- W2136964613 cites W1983788760 @default.
- W2136964613 cites W1986223229 @default.
- W2136964613 cites W1986799592 @default.
- W2136964613 cites W1993007361 @default.
- W2136964613 cites W1993776397 @default.
- W2136964613 cites W1993977067 @default.
- W2136964613 cites W1994244683 @default.
- W2136964613 cites W1998366922 @default.
- W2136964613 cites W2002859104 @default.
- W2136964613 cites W2003398981 @default.
- W2136964613 cites W2003618140 @default.
- W2136964613 cites W2005278376 @default.
- W2136964613 cites W2005997590 @default.
- W2136964613 cites W2010139413 @default.
- W2136964613 cites W2010712016 @default.
- W2136964613 cites W2011627995 @default.
- W2136964613 cites W2013999923 @default.
- W2136964613 cites W2015363245 @default.
- W2136964613 cites W2015680138 @default.
- W2136964613 cites W2020770674 @default.
- W2136964613 cites W2022071216 @default.
- W2136964613 cites W2023633642 @default.
- W2136964613 cites W2024205812 @default.
- W2136964613 cites W2026132129 @default.
- W2136964613 cites W2026870302 @default.
- W2136964613 cites W2027647210 @default.
- W2136964613 cites W2028053717 @default.
- W2136964613 cites W2029340753 @default.
- W2136964613 cites W2031255714 @default.
- W2136964613 cites W2034501059 @default.
- W2136964613 cites W2037764002 @default.
- W2136964613 cites W2037909149 @default.
- W2136964613 cites W2041977337 @default.
- W2136964613 cites W2043214834 @default.
- W2136964613 cites W2043700769 @default.
- W2136964613 cites W2048405963 @default.
- W2136964613 cites W2049046749 @default.
- W2136964613 cites W2050102701 @default.
- W2136964613 cites W2052443018 @default.
- W2136964613 cites W2057771908 @default.
- W2136964613 cites W2063821423 @default.
- W2136964613 cites W2066283904 @default.
- W2136964613 cites W2075950673 @default.
- W2136964613 cites W2077300197 @default.
- W2136964613 cites W2079798038 @default.
- W2136964613 cites W2081036172 @default.
- W2136964613 cites W2082338210 @default.
- W2136964613 cites W2088061351 @default.
- W2136964613 cites W2089993897 @default.
- W2136964613 cites W2093846035 @default.
- W2136964613 cites W2095298207 @default.
- W2136964613 cites W2097409296 @default.
- W2136964613 cites W2107010521 @default.
- W2136964613 cites W2110356249 @default.
- W2136964613 cites W2114057107 @default.
- W2136964613 cites W2123352288 @default.
- W2136964613 cites W2129703197 @default.
- W2136964613 cites W2131286481 @default.
- W2136964613 cites W2157805869 @default.
- W2136964613 cites W4211116418 @default.
- W2136964613 cites W576736898 @default.
- W2136964613 doi "https://doi.org/10.1063/1.3268779" @default.
- W2136964613 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19968367" @default.
- W2136964613 hasPublicationYear "2009" @default.
- W2136964613 type Work @default.
- W2136964613 sameAs 2136964613 @default.
- W2136964613 citedByCount "28" @default.
- W2136964613 countsByYear W21369646132012 @default.
- W2136964613 countsByYear W21369646132013 @default.
- W2136964613 countsByYear W21369646132014 @default.
- W2136964613 countsByYear W21369646132015 @default.
- W2136964613 countsByYear W21369646132016 @default.
- W2136964613 countsByYear W21369646132017 @default.
- W2136964613 countsByYear W21369646132018 @default.
- W2136964613 countsByYear W21369646132019 @default.
- W2136964613 countsByYear W21369646132020 @default.
- W2136964613 countsByYear W21369646132021 @default.
- W2136964613 countsByYear W21369646132022 @default.
- W2136964613 crossrefType "journal-article" @default.
- W2136964613 hasAuthorship W2136964613A5030290474 @default.
- W2136964613 hasAuthorship W2136964613A5040102566 @default.
- W2136964613 hasAuthorship W2136964613A5065669622 @default.
- W2136964613 hasBestOaLocation W21369646132 @default.
- W2136964613 hasConcept C112887158 @default.
- W2136964613 hasConcept C15920480 @default.