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- W2136984497 abstract "Treatment of the semicarbazones 4-MeC6H4C(Me)NN(H)C(O)NH2 a, 3,4-Me2C6H3C(Me)NN(H)C(O)NH2 b and C6H5C(Et)NN(H)C(O)NH2 c, gave the [C,N,O] cyclometallated compounds [Pd{4-MeC6H3C(Me)NN(H)C(O)NH2}(Cl)] 1a, [Pd{3,4-Me2C6H2C(Me)NN(H)C(O)NH2}(Cl)] 1b and [Pd{C6H4C(Et)NN(H)C(O)NH2}(Cl)] 1c, after CH activation. Treatment of compounds 1a, 1b, and 1c with silver perchlorate followed by treatment with tertiary diphosphine ligands gave the dinuclear [C,N,O] cyclometallated compounds [{Pd[4-MeC6H3C(Me)NN(H)C(O)NH2]}2(μ-L)][ClO4]2 2a–7a, [{Pd[3,4-Me2C6H2C(Me)NN(H)C(O)NH2]}2(μ-L)][ClO4]2 2b–7b, [{Pd[C6H4C(Et)NN(H)C(O)NH2]}2(μ-L)][ClO4]2 2c–7c, [L=Ph2P(CH2)4PPh2 (dppb), Ph2P(CH2)3PPh2 (dppp), Ph2P(CH2)2PPh2 (dppe), trans-Ph2PCHCHPPh2 (trans-dppe), Ph2PC(CH2)PPh2 (vdpp) and Ph2PCH2PPh2 (dppm)] as 1:2 electrolytes. Reaction of 1a and 1c with diphosphines gave the dinuclear [C,N] cyclometallated compounds [{Pd[4-MeC6H3C(Me)NN(H)C(O)NH2](Cl)}2(μ-L)] 8a, 9a, [{Pd[C6H4C(Et)NN(H)C(O)NH2](Cl)}2(μ-L)] 8c, 9c, [L=Ph2P(CH2)3PPh2 (dppp) and Ph2P(CH2)4PPh2 (dppb)]. The complexes were characterised by their elemental analysis (C,H,N) and by IR and 31P{1H} and 1H-NMR data, and [{Pd[C6H4C(Et)NN(H)C(O)NH2]}2(μ-Ph2P(CH2)3PPh2)][ClO4]2 (3c) was characterised crystallographically." @default.
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- W2136984497 date "1998-04-01" @default.
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- W2136984497 title "Cylometallated semicarbazone complexes of palladium(II). Crystal and molecular structure of [{Pd[C6H4C(Et)NN(H)C(O)NH2]}2(μ-Ph2P(CH2)3PPh2)][ClO4]2" @default.
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- W2136984497 doi "https://doi.org/10.1016/s0022-328x(97)00668-2" @default.
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