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- W2136989557 abstract "A new family of magnetic semiconductors, K2Cd3(1-x)Mn3xS4, prepared from molten K2Sx is reported. For x ≤ 0.6, the compounds crystallize in the K2Cd3S4 structure type. The cell volumes of the series obey Vegard's Law for solid solutions. The compounds range in color from yellow through orange brown to red and possess platelike morphologies. A structural transformation occurs between x = 0.7 and x = 0.9. Red plates of K2Cd0.4Mn2.6S4 (x = 0.87) crystallize in the space group Ccca with a = 5.9217(8) A, b = 13.531(1) A, c = 11.0696(8) A, and V = 887.0(1) A3. The end member, K2Mn3S4, crystallizes in the space group Ccca with a = 11.0637(7) A, b = 26.830(2) A c = 5.8180(4) A, and V = 1727 A3. For x ≤ 0.6, the compounds form as (M3S4)n2n- layers, interspersed by K+ cations. These layers are composed only of M3S42- units shaped like truncated cubes. When x = 0.87, a new structure related to that of Cs2Mn3S4 is observed. The end member of the series (i.e., x = 1) K2Mn3S4 is revealed to have a related yet surprisin..." @default.
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- W2136989557 date "2010-05-23" @default.
- W2136989557 modified "2023-09-28" @default.
- W2136989557 title "ChemInform Abstract: Photoluminescence and Magnetism in the New Magnetic Semiconductors: K2Cd3(1-x)Mn3xS4." @default.
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- W2136989557 doi "https://doi.org/10.1002/chin.200149008" @default.
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