Matches in SemOpenAlex for { <https://semopenalex.org/work/W2137112559> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2137112559 endingPage "1322" @default.
- W2137112559 startingPage "1316" @default.
- W2137112559 abstract "Transition metal complexes of novel mono- and di-ferrocene-substituted porphyrins have been synthesized and characterized by structural and electrochemical methods. The X-ray structures of Mn(FPTTP)Cl and Mn(DFTTP)Cl showed the distorted square pyramidal coordination geometry with syn configuration of chloride and ferrocenyl substituents. The electrochemistry of ferrocene-substituted porphyrins and their metal complexes has been determined to elucidate the π-conjugation effect of the porphyrin ring. The ferrocenyl group of H 2 FPTTP underwent a reversible one-electron transfer process at 0.30 V, indicating the good electron donating effect of the phorphyrin ring to the ferrocene substituent. The redox potential of the ferrocenyl subunit and porphyrin ring was affected by the central metal ions of the metalloporphyrins, that is, Zn(II) and Ni(II) made the oxidation of ferrocene much easier and Mn(III) made it harder. The ferrocene subunits of H 2 DFTTP interacted electrochemically with each other with peak splitting of 0.21 V. The strength of the electrochemical interactions between the two ferrocenyl substituents can be controlled by central metal ions of metalloporphyrins." @default.
- W2137112559 created "2016-06-24" @default.
- W2137112559 creator A5025028170 @default.
- W2137112559 creator A5036998189 @default.
- W2137112559 creator A5052269526 @default.
- W2137112559 creator A5058619428 @default.
- W2137112559 creator A5076494101 @default.
- W2137112559 creator A5091185670 @default.
- W2137112559 date "2001-01-01" @default.
- W2137112559 modified "2023-09-23" @default.
- W2137112559 title "X-ray Structure and Electrochemical Properties of Ferrocene-Substituted Metalloporphyrins" @default.
- W2137112559 cites W1522110495 @default.
- W2137112559 cites W647865620 @default.
- W2137112559 hasPublicationYear "2001" @default.
- W2137112559 type Work @default.
- W2137112559 sameAs 2137112559 @default.
- W2137112559 citedByCount "1" @default.
- W2137112559 crossrefType "journal-article" @default.
- W2137112559 hasAuthorship W2137112559A5025028170 @default.
- W2137112559 hasAuthorship W2137112559A5036998189 @default.
- W2137112559 hasAuthorship W2137112559A5052269526 @default.
- W2137112559 hasAuthorship W2137112559A5058619428 @default.
- W2137112559 hasAuthorship W2137112559A5076494101 @default.
- W2137112559 hasAuthorship W2137112559A5091185670 @default.
- W2137112559 hasConcept C123669783 @default.
- W2137112559 hasConcept C147789679 @default.
- W2137112559 hasConcept C155647269 @default.
- W2137112559 hasConcept C17525397 @default.
- W2137112559 hasConcept C178790620 @default.
- W2137112559 hasConcept C179104552 @default.
- W2137112559 hasConcept C185592680 @default.
- W2137112559 hasConcept C188027245 @default.
- W2137112559 hasConcept C199164860 @default.
- W2137112559 hasConcept C2777237805 @default.
- W2137112559 hasConcept C2778689049 @default.
- W2137112559 hasConcept C2779480358 @default.
- W2137112559 hasConcept C2780378348 @default.
- W2137112559 hasConcept C52859227 @default.
- W2137112559 hasConcept C544153396 @default.
- W2137112559 hasConcept C55904794 @default.
- W2137112559 hasConcept C75473681 @default.
- W2137112559 hasConcept C8010536 @default.
- W2137112559 hasConceptScore W2137112559C123669783 @default.
- W2137112559 hasConceptScore W2137112559C147789679 @default.
- W2137112559 hasConceptScore W2137112559C155647269 @default.
- W2137112559 hasConceptScore W2137112559C17525397 @default.
- W2137112559 hasConceptScore W2137112559C178790620 @default.
- W2137112559 hasConceptScore W2137112559C179104552 @default.
- W2137112559 hasConceptScore W2137112559C185592680 @default.
- W2137112559 hasConceptScore W2137112559C188027245 @default.
- W2137112559 hasConceptScore W2137112559C199164860 @default.
- W2137112559 hasConceptScore W2137112559C2777237805 @default.
- W2137112559 hasConceptScore W2137112559C2778689049 @default.
- W2137112559 hasConceptScore W2137112559C2779480358 @default.
- W2137112559 hasConceptScore W2137112559C2780378348 @default.
- W2137112559 hasConceptScore W2137112559C52859227 @default.
- W2137112559 hasConceptScore W2137112559C544153396 @default.
- W2137112559 hasConceptScore W2137112559C55904794 @default.
- W2137112559 hasConceptScore W2137112559C75473681 @default.
- W2137112559 hasConceptScore W2137112559C8010536 @default.
- W2137112559 hasIssue "12" @default.
- W2137112559 hasLocation W21371125591 @default.
- W2137112559 hasOpenAccess W2137112559 @default.
- W2137112559 hasPrimaryLocation W21371125591 @default.
- W2137112559 hasRelatedWork W139597097 @default.
- W2137112559 hasRelatedWork W1777736414 @default.
- W2137112559 hasRelatedWork W1963732922 @default.
- W2137112559 hasRelatedWork W1980255930 @default.
- W2137112559 hasRelatedWork W1980487114 @default.
- W2137112559 hasRelatedWork W1993508825 @default.
- W2137112559 hasRelatedWork W2002332185 @default.
- W2137112559 hasRelatedWork W2020095354 @default.
- W2137112559 hasRelatedWork W2032065601 @default.
- W2137112559 hasRelatedWork W2037222128 @default.
- W2137112559 hasRelatedWork W2043741652 @default.
- W2137112559 hasRelatedWork W2051541407 @default.
- W2137112559 hasRelatedWork W2062642861 @default.
- W2137112559 hasRelatedWork W2062871983 @default.
- W2137112559 hasRelatedWork W2066939903 @default.
- W2137112559 hasRelatedWork W2076578682 @default.
- W2137112559 hasRelatedWork W2077553094 @default.
- W2137112559 hasRelatedWork W2089449199 @default.
- W2137112559 hasRelatedWork W2950346509 @default.
- W2137112559 hasRelatedWork W2952251002 @default.
- W2137112559 hasVolume "22" @default.
- W2137112559 isParatext "false" @default.
- W2137112559 isRetracted "false" @default.
- W2137112559 magId "2137112559" @default.
- W2137112559 workType "article" @default.