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- W2137177360 abstract "A new zinc(II) complex with a condensed hydroxynaphthyl pyridine (SPHN) as the coordinated ligand has been synthesized for the selective recognition of pyrophosphate (PPi) over other anions including phosphate in a mixed aqueous solution. The fluorescence enhancement of SPHN in association with Zn2+ ions is quenched in the presence of intracellular pyrophosphate. This phenomenon is utilized in the construction of a logic gate. The binding of SPHN with Zn2+ and its displacement by PPi have been established by photophysical investigation and supported by the DFT level of studies. The development of blue fluorescence in the {SPNH–Zn} complex upon binding of zinc with SPHN is shown to be useful as a nucleus marker in a cell similar to the commercially available staining compound, DAPI (diamino-2-phenylindole)." @default.
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- W2137177360 date "2014-06-23" @default.
- W2137177360 modified "2023-10-11" @default.
- W2137177360 title "Pyrophosphate selective fluorescent chemosensors: cascade recognition of nuclear stain mimicking DAPI" @default.
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- W2137177360 doi "https://doi.org/10.1039/c4dt01262c" @default.
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