FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2137257952> ?p ?o ?g. }

• W2137257952 endingPage "54" @default.
• W2137257952 startingPage "49" @default.
• W2137257952 abstract "A new fluorescent molecule 1,7-diazaperylene (DP) has been investigated by means of time-resolved and steady-state polarized fluorescence spectroscopy, as well as X-ray spectroscopy. Absorption and fluorescence spectra of DP in solution are similar to those of perylene. However, absorption and fluorescence spectra of 2,8-dimethoxy DP and 2,8-dipentyloxy DP in solution are red-shifted by ca. 55 nm relative to perylene. The fluorescence decay of DP is exponential with a lifetime of 5.1 ns in ethanol, 4.9 ns in glycerol and 4.3 ns in paraffin oil. The radiative lifetime in ethanol was calculated to be 6.3 ns for DP, 8.0 ns for 2,8-dimethoxy DP and 7.6 ns for 2,8-dipentyloxy DP. The calculated fluorescence quantum yields of 0.8 for DP and its alkoxy derivatives in ethanol, are in good agreement with those obtained from measurements. The calculated Förster radius is 37.2 ± 1 Å for DP and 41.9 ± 1 Å for its alkoxy derivatives in ethanol. Examining the S0↔ S1 transition, we obtain a limiting fluorescence anisotropy of r0≈ 0.38 for DP and its alkoxy derivatives. The rotational rates of DP in paraffin oil and glycerol were compared to that of perylene. In paraffin oil both molecules show an almost identical biexponential decay of the fluorescence anisotropy, which is compatible with a rotational motion like an oblate ellipsoid. The fluorescence anisotropy is monoexponential for DP in glycerol, and DP appears to rotate like a spherical particle while perylene in glycerol appears to rotate like an oblate ellipsoid. Moreover, the rotational diffusion constant, corresponding to rotation about an axis in the aromatic plane (D⊥), is the same for both DP and perylene in glycerol." @default.
• W2137257952 created "2016-06-24" @default.
• W2137257952 creator A5006683622 @default.
• W2137257952 creator A5030662404 @default.
• W2137257952 creator A5032403377 @default.
• W2137257952 creator A5044114439 @default.
• W2137257952 creator A5070199183 @default.
• W2137257952 creator A5080895485 @default.
• W2137257952 date "1993-01-01" @default.
• W2137257952 modified "2023-09-26" @default.
• W2137257952 title "Photophysics, molecular reorientation in solution and X-ray structure of a new fluorescent probe, 1,7-diazaperylene" @default.
• W2137257952 cites W1967604899 @default.
• W2137257952 cites W1984881210 @default.
• W2137257952 cites W1987221264 @default.
• W2137257952 cites W1990064590 @default.
• W2137257952 cites W1997030949 @default.
• W2137257952 cites W1999815869 @default.
• W2137257952 cites W2009353098 @default.
• W2137257952 cites W2020366542 @default.
• W2137257952 cites W2028258211 @default.
• W2137257952 cites W2028839367 @default.
• W2137257952 cites W2031853246 @default.
• W2137257952 cites W2032461276 @default.
• W2137257952 cites W2045103863 @default.
• W2137257952 cites W2055897820 @default.
• W2137257952 cites W2058883479 @default.
• W2137257952 cites W2059699458 @default.
• W2137257952 cites W2075201777 @default.
• W2137257952 cites W2078039581 @default.
• W2137257952 cites W2089158442 @default.
• W2137257952 cites W2111091421 @default.
• W2137257952 cites W2117649468 @default.
• W2137257952 cites W2132028777 @default.
• W2137257952 doi "https://doi.org/10.1039/ft9938900049" @default.
• W2137257952 hasPublicationYear "1993" @default.
• W2137257952 type Work @default.
• W2137257952 sameAs 2137257952 @default.
• W2137257952 citedByCount "37" @default.
• W2137257952 countsByYear W21372579522013 @default.
• W2137257952 countsByYear W21372579522014 @default.
• W2137257952 countsByYear W21372579522015 @default.
• W2137257952 countsByYear W21372579522016 @default.
• W2137257952 countsByYear W21372579522017 @default.
• W2137257952 countsByYear W21372579522018 @default.
• W2137257952 countsByYear W21372579522020 @default.
• W2137257952 countsByYear W21372579522022 @default.
• W2137257952 crossrefType "journal-article" @default.
• W2137257952 hasAuthorship W2137257952A5006683622 @default.
• W2137257952 hasAuthorship W2137257952A5030662404 @default.
• W2137257952 hasAuthorship W2137257952A5032403377 @default.
• W2137257952 hasAuthorship W2137257952A5044114439 @default.
• W2137257952 hasAuthorship W2137257952A5070199183 @default.
• W2137257952 hasAuthorship W2137257952A5080895485 @default.
• W2137257952 hasBestOaLocation W21372579522 @default.
• W2137257952 hasConcept C111357860 @default.
• W2137257952 hasConcept C113196181 @default.
• W2137257952 hasConcept C119824511 @default.
• W2137257952 hasConcept C120665830 @default.
• W2137257952 hasConcept C121332964 @default.
• W2137257952 hasConcept C125287762 @default.
• W2137257952 hasConcept C133279788 @default.
• W2137257952 hasConcept C158711907 @default.
• W2137257952 hasConcept C159985019 @default.
• W2137257952 hasConcept C178790620 @default.
• W2137257952 hasConcept C185592680 @default.
• W2137257952 hasConcept C192562407 @default.
• W2137257952 hasConcept C2776294167 @default.
• W2137257952 hasConcept C2778639546 @default.
• W2137257952 hasConcept C2779189646 @default.
• W2137257952 hasConcept C32891209 @default.
• W2137257952 hasConcept C32909587 @default.
• W2137257952 hasConcept C62520636 @default.
• W2137257952 hasConcept C75473681 @default.
• W2137257952 hasConcept C91881484 @default.
• W2137257952 hasConceptScore W2137257952C111357860 @default.
• W2137257952 hasConceptScore W2137257952C113196181 @default.
• W2137257952 hasConceptScore W2137257952C119824511 @default.
• W2137257952 hasConceptScore W2137257952C120665830 @default.
• W2137257952 hasConceptScore W2137257952C121332964 @default.
• W2137257952 hasConceptScore W2137257952C125287762 @default.
• W2137257952 hasConceptScore W2137257952C133279788 @default.
• W2137257952 hasConceptScore W2137257952C158711907 @default.
• W2137257952 hasConceptScore W2137257952C159985019 @default.
• W2137257952 hasConceptScore W2137257952C178790620 @default.
• W2137257952 hasConceptScore W2137257952C185592680 @default.
• W2137257952 hasConceptScore W2137257952C192562407 @default.
• W2137257952 hasConceptScore W2137257952C2776294167 @default.
• W2137257952 hasConceptScore W2137257952C2778639546 @default.
• W2137257952 hasConceptScore W2137257952C2779189646 @default.
• W2137257952 hasConceptScore W2137257952C32891209 @default.
• W2137257952 hasConceptScore W2137257952C32909587 @default.
• W2137257952 hasConceptScore W2137257952C62520636 @default.
• W2137257952 hasConceptScore W2137257952C75473681 @default.
• W2137257952 hasConceptScore W2137257952C91881484 @default.
• W2137257952 hasIssue "1" @default.
• W2137257952 hasLocation W21372579521 @default.
• W2137257952 hasLocation W21372579522 @default.
• W2137257952 hasOpenAccess W2137257952 @default.

• next