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- W2137303553 abstract "The construction and sensing performance of solid-state potentiometric sensors using a natrium superionic conductor (NASICON) as solid electrolyte are reported. Dense ceramic pellets with a pure NASICON crystal phase were produced by a solid-state reaction method using a modified procedure. The NASICON surface on the Pt sensing electrode side was modified with a layer as an auxiliary phase using a melting-quenching method. By the same method, the other surface of the NASICON was modified with an AgCl layer and was connected with an Ag wire as a reference electrode. An air/Pt quasi-reference electrode was fabricated by exposing the Pt black attached NASICON surface to the ambient. Both sensor devices using air/Pt and Ag/AgCl reference electrodes were investigated for sensing. The two sensor designs exhibited Nernstian behavior, fast response, stability, and reproducibility. The Ag/AgCl reference electrode provides an all-solid-state design for the sensor device without the need for a reference gas with fixed composition or a hermetic seal separating the reference electrode from the sample gas. A sensing mechanism is discussed. © 2004 The Electrochemical Society. All rights reserved." @default.
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- W2137303553 date "2004-01-01" @default.
- W2137303553 modified "2023-10-13" @default.
- W2137303553 title "Modification of NASICON Solid Electrolyte for NO[sub x] Measurements" @default.
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- W2137303553 doi "https://doi.org/10.1149/1.1647577" @default.
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