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• W2137465548 abstract "The intermolecular potential between the ground electronic state of H2O (1A1) and the H+ projectile is obtained from SCF calculations of near-Hartree-Fock quality for the rigid rotor (RR) target molecule and within the Born-Oppenheimer (BO) approximation. The symmetry-adapted, multipolar expansion of the potential energy surface (PES) produces the leading coefficients which are further extrapolated via the perturbation expressions for the induction and polarization forces in the long-range region. The rotationally inelastic collision processes for this asymmetric top rotor are computed, at the energies examined in recent molecular beam experiments, in order to estimate the contribution of (T,R) energy transfer in the direct channels. The quantum dynamics was treated within the infinite-order-sudden (IOS) approximation and both rotationally summed and partial inelastic cross sections are analysed and discussed." @default.
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• W2137465548 date "1991-11-14" @default.
• W2137465548 modified "2023-09-23" @default.
• W2137465548 title "Rotational energy transfer in ion-molecule scattering. I. The proton-water example" @default.
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• W2137465548 doi "https://doi.org/10.1088/0953-4075/24/21/008" @default.
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