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- W2137649079 abstract "We present the study on the structural and the magnetic properties of LiFePO <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> and LiFe <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>0.8</sub> Co <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>0.2</sub> PO <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> . The crystal structure was determined to be orthorhombic with space group <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>P</i> nma by Rietveld refinement method. We have observed the increase in the lattice constants with Co <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2+</sup> ion substituted. The Mossbauer spectra of olivine LiFePO <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> and LiFe <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>0.8</sub> Co <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>0.2</sub> PO <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> have shown distorted line broadening below <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>T</i> <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>N</sub> . In order to explain the observed line broadening, we have analyzed the Mossbauer spectra by considering the full Hamiltonian for the <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>57</sup> Fe nucleus, and both the magnetic dipole and the electric quadrupole interactions. Also, we have observed the anomalous change in the electric quadrupole splitting near the <i xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>T</i> <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>N</sub> ." @default.
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- W2137649079 date "2009-06-01" @default.
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- W2137649079 title "Investigation of Microscopic Crystal Field in Co-Doped Lithium-Iron Phosphate" @default.
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- W2137649079 doi "https://doi.org/10.1109/tmag.2009.2018897" @default.
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