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- W2137781302 abstract "The first organocatalytic Mannich reaction of 5H-oxazol-4-ones with various readily prepared aryl- and alkylsulfonimides has been developed. Two commercially available pseudoenantiomeric Cinchona alkaloids-derived tertiary amine/ureas have been demonstrated as the most efficient catalysts to access the opposite enantiomers of the Mannich products with equally excellent enantio- and diastereoselectivities. From the Mannich adducts, important α-methyl-α-hydroxy-β-amino acid derivatives, such as the α-methylated C-13 side chain of taxol and taxotere, can be conveniently prepared." @default.
- W2137781302 created "2016-06-24" @default.
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- W2137781302 date "2013-05-15" @default.
- W2137781302 modified "2023-10-18" @default.
- W2137781302 title "Organocatalytic Asymmetric Mannich Reactions of 5<i>H</i>-Oxazol-4-ones: Highly Enantio- and Diastereoselective Synthesis of Chiral α-Alkylisoserine Derivatives" @default.
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- W2137781302 doi "https://doi.org/10.1002/adsc.201300135" @default.
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